ALI, M., D. DUTTA, S. BISWAS, Jaromír MAREK and A. D. JANA. The first crystallographic observation of up to the third hydration layer of Cu(II) ion in an unusual 'water-cation layer' templated by an Anderson polyoxometallate. CRYSTENGCOMM. Cambridge, UK: RSC Publishing, 2009, vol. 11, No 12, p. 2608-2610. ISSN 1466-8033.
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Basic information
Original name The first crystallographic observation of up to the third hydration layer of Cu(II) ion in an unusual 'water-cation layer' templated by an Anderson polyoxometallate
Name in Czech První krystalografické pozorování 3. hydratační vrstvy kolem měďnatého iontu v neobvyklé vrstvě "voda-kationt" formované Anderson polyoxometaláty
Authors ALI, M. (356 India), D. DUTTA (356 India), S. BISWAS (356 India), Jaromír MAREK (203 Czech Republic, guarantor, belonging to the institution) and A. D. JANA (356 India).
Edition CRYSTENGCOMM, Cambridge, UK, RSC Publishing, 2009, 1466-8033.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 4.183
RIV identification code RIV/00216224:14310/09:00038650
Organization unit Faculty of Science
UT WoS 000271864700016
Keywords (in Czech) supramolekulární struktura; měď; vodíková vazba
Keywords in English hydration; copper; hydrogen bond; supramolecular structure
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 2/5/2012 13:09.
Abstract
This constitutes the first crystallographic observation of hydrated Cu(II) ion retaining up to its third hydration layer which, along with the chair form water hexamer, builds up a unique water - cation layer. Moreover, an unprecedented supramolecular honeycomb network of [Cu(phen)3]2+ units templated by Anderson polyoxometallate units occupy the intervening spaces between successive water layers.
Abstract (in Czech)
Článek popisuje krystalovou strukturu komplexu s neobvyklou 3. hydratační vrstvou kolem měďnatého iontu.
Links
MSM0021622410, plan (intention)Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures
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