TRÁVNÍČEK, Z. and Jaromír MAREK. X-ray structural characterizations of the reaction products between ZnCl2 and 6-benzylaminopurine derivatives in different acidic conditions. Journal of Molecular Structure. Nizozemsko: Elsevier Science, 2009, vol. 933, 1-3, p. 148-155. ISSN 0022-2860.
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Basic information
Original name X-ray structural characterizations of the reaction products between ZnCl2 and 6-benzylaminopurine derivatives in different acidic conditions
Name in Czech RTG strukturní charakterizace produktu reakce mezi ZnCl2 a deriváty 6-benzylaminopurinů za různých kyselostních podmínek
Authors TRÁVNÍČEK, Z. (203 Czech Republic) and Jaromír MAREK (203 Czech Republic, guarantor).
Edition Journal of Molecular Structure, Nizozemsko, Elsevier Science, 2009, 0022-2860.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Netherlands
Confidentiality degree is not subject to a state or trade secret
WWW URL
Impact factor Impact factor: 1.551
RIV identification code RIV/00216224:14310/09:00038662
Organization unit Faculty of Science
UT WoS 000269472400021
Keywords (in Czech) zinecnate kmomplexy; 6-Benzylaminopurin; krystalova struktura
Keywords in English Zinc(II) complexes; Tautomerism; Protonation; 6-Benzylaminopurine; Crystal structures
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 25/1/2010 12:58.
Abstract
The reaction between ZnCl2 and the corresponding 6-benzylaminopurine derivative, Ln, [where L1 = 6-(4- fluorobenzylamino)purine, L2 = 6-(2-fluorobenzylamino)purine or L3 = 6-(4-chlorobenzylamino)purine] in 0.1 M or 2 M HCl afforded various products in dependence on a pH of the reaction medium. X-ray structures of the reaction products have been determined by a single crystal X-ray analysis. Moreover, the compounds have been characterized by elemental analyses (C, H, N), FTIR and Raman spectroscopies, and thermogravimetric (TG) and differential thermal (DTA) analyses.
Abstract (in Czech)
Reakce mezi ZnCl2 a deriváty 6-benzylaminopurinů, [L1 = 6-(4- fluorobenzylamino)purin, L2 = 6-(2-fluorobenzylamino)purin nebo L3 = 6-(4-chlorobenzylamino)purin] v 0.1 M nebo 2 M HCl vedly v závislosti na pH reakčního média k různým reakčním produktům. Vlastnosti produktů byly studovány rozličnými fyzikálně chemickými metodami. Struktury byly popisovány monokrystalovou difrakcí RTG.
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MSM0021622415, plan (intention)Name: Molekulární podstata buněčných a tkáňových regulací
Investor: Ministry of Education, Youth and Sports of the CR, Molecular basis of cell and tissue regulations
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