Condensation of aromatic aldehydes with N,N-dimethylacetamide in presence of dialkyl carbonates as dehydrating agents

WEIDLICH, Tomáš, Lubomír PROKEŠ, Aleš RŮŽIČKA and Zdeňka PADĚLKOVÁ. Condensation of aromatic aldehydes with N,N-dimethylacetamide in presence of dialkyl carbonates as dehydrating agents. Monatshefte fuer Chemie, Chemical Monthly. Wien: Springer-Verlag, 2010, vol. 141, No 2, p. 205-211, 6 pp. ISSN 0026-9247.

Basic information

Original name

Condensation of aromatic aldehydes with N,N-dimethylacetamide in presence of dialkyl carbonates as dehydrating agents

Authors

WEIDLICH, Tomáš (203 Czech Republic, guarantor), Lubomír PROKEŠ (203 Czech Republic, belonging to the institution), Aleš RŮŽIČKA (203 Czech Republic) and Zdeňka PADĚLKOVÁ (203 Czech Republic)

Edition

Monatshefte fuer Chemie, Chemical Monthly, Wien, Springer-Verlag, 2010, 0026-9247

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Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.356

RIV identification code

RIV/00216224:14310/10:00043399

Organization unit

Faculty of Science

UT WoS

000274730600009

Keywords in English

CC bond formation - Aldol type reaction - Alkylation - AOX removal - AlNi alloy

Tags

RIV-OK

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Abstract

V originále

Reactions of benzaldehydes with excess N,N dimethylacetamide in the presence of diethyl carbonate as dehydrating agent and a base gave (E)N,N dimethylcinnamamides in good yields. If hydroxybenzaldehydes are used as substrates the reaction is accompanied by alkylation.