2010
T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes
KALETA, Jiří; Josef MICHL and Ctibor MAZALBasic information
Original name
T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes
Name in Czech
Molekulární stavební bloky kombinací bridgehead a bridge substituce na bicyklo[1.1.1]pentanech
Authors
KALETA, Jiří; Josef MICHL and Ctibor MAZAL
Edition
Journal of Organic Chemistry, 2010, 0022-3263
Other information
Language
English
Type of outcome
Article in a journal
Field of Study
10401 Organic chemistry
Country of publisher
United States of America
Confidentiality degree
is not subject to a state or trade secret
References:
Impact factor
Impact factor: 4.002
RIV identification code
RIV/00216224:14310/10:00051340
Organization unit
Faculty of Science
UT WoS
000275884400024
Keywords (in Czech)
organic synthesis;bicyclopentanes;strained compounds;molecular building blocks
Keywords in English
organic synthesis;bicyclopentanes;strained compounds;molecular building blocks
Tags
International impact, Reviewed
Changed: 23/3/2012 12:09, Mgr. Anísa Kabarová
In the original language
Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials. For good chemical connectivity in the axial direction, carboxylates, ethynyls, and acetylsulfanyl groups were installed at the bridgeheads. Quinoxalines were attached in the transverse direction through a highly reactive alpha-diketone system located at the bridges.
In Czech
Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials. For good chemical connectivity in the axial direction, carboxylates, ethynyls, and acetylsulfanyl groups were installed at the bridgeheads. Quinoxalines were attached in the transverse direction through a highly reactive alpha-diketone system located at the bridges.
Links
| ME09114, research and development project |
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