TRNKOVÁ, Libuše, Ladislav NOVOTNÝ, Nuria SERRANO, Kateřina KLOSOVÁ and Petra POLÁŠKOVÁ. Elimination Voltammetry of Miniaturized Mercury Drop Electrodes. Electroanalysis. 2010, vol. 22, No 16, p. 1873-1880. ISSN 1521-4109. |
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@article{901168, author = {Trnková, Libuše and Novotný, Ladislav and Serrano, Nuria and Klosová, Kateřina and Polášková, Petra}, article_number = {16}, keywords = {Elimination voltammetry with linear scan (EVLS); Linear sweep voltammetry (LSV); Mini-drop electrodes; Cottrell equation; Spherical diffusion; Voltammetry; Hydrogen evolution}, language = {eng}, issn = {1521-4109}, journal = {Electroanalysis}, title = {Elimination Voltammetry of Miniaturized Mercury Drop Electrodes}, volume = {22}, year = {2010} }
TY - JOUR ID - 901168 AU - Trnková, Libuše - Novotný, Ladislav - Serrano, Nuria - Klosová, Kateřina - Polášková, Petra PY - 2010 TI - Elimination Voltammetry of Miniaturized Mercury Drop Electrodes JF - Electroanalysis VL - 22 IS - 16 SP - 1873-1880 EP - 1873-1880 SN - 15214109 KW - Elimination voltammetry with linear scan (EVLS) KW - Linear sweep voltammetry (LSV) KW - Mini-drop electrodes KW - Cottrell equation KW - Spherical diffusion KW - Voltammetry KW - Hydrogen evolution N2 - Elimination voltammetry with linear scan (EVLS) in connection with renewed mini- drop mercury electrodes provides valuable information about the character and kinetics of processes at electrode/electrolyte interfaces. Based on the experiment related to the hydrogen evolution, it is presented that the EVLS is more sensitive than other voltammetric methods. Using miniaturized mercury electrodes, the EVLS is capable of detecting the effect of spherical diffusion associated with both the scan rates and the size of an electrode drop. ER -
TRNKOVÁ, Libuše, Ladislav NOVOTNÝ, Nuria SERRANO, Kateřina KLOSOVÁ and Petra POLÁŠKOVÁ. Elimination Voltammetry of Miniaturized Mercury Drop Electrodes. \textit{Electroanalysis}. 2010, vol.~22, No~16, p.~1873-1880. ISSN~1521-4109.
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