J 2011

A Triangular Macrocycle Altering Planar and Bulky Sections in Its Molecular Backbone

KALETA, Jiří and Ctibor MAZAL

Basic information

Original name

A Triangular Macrocycle Altering Planar and Bulky Sections in Its Molecular Backbone

Authors

KALETA, Jiří (203 Czech Republic, belonging to the institution) and Ctibor MAZAL (203 Czech Republic, guarantor, belonging to the institution)

Edition

Organic Letters, Washington D.C., USA, American Chemical Society, 2011, 1523-7060

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 5.862

RIV identification code

RIV/00216224:14310/11:00052038

Organization unit

Faculty of Science

DOI

UT WoS

000288148800016

Keywords in English

SHAPE-PERSISTENT MACROCYCLES; SUPRAMOLECULAR CHEMISTRY

Tags

Změněno: 20/4/2012 10:12, Ing. Andrea Mikešková

Abstract

ORIG CZ

V originále

A triangular macrocyclic molecule has been synthesized which consists of substituted phenanthrene vertices interconnected by 1,3-diethynylbicyclo[1.1.1]pentane sides. The molecule is the very first example of exploiting the bicyclopentane motif in the construction of a shape persistent macrocycle's backbone. It carries new features such as bulkiness, nonconjugated sigma-bonding, and a certain conformational flexibility due to its easy longitudinal rotation. We have used some of the features in order to rationalize the observed tendency of the compound to form films on various surfaces.

In Czech

Byla syntetizována trojúhelníková makrocyklická molekula složená z fenanthrenových vrcholů spojených stranami z 1,3-ethynylbicykl[1.1.1]pentanu. Jde o první příklad shape-persistentního makrocyklu využívající stavební motiv bicyklopentanu.

Links

ME09114, research and development project
Name: Spolupráce v oblasti energie a nanověd: USA a Evropa (Collaboration in Energy and Nanoscience)
Investor: Ministry of Education, Youth and Sports of the CR, Collaboration in Energy and Nanoscience, Research and Development Programme KONTAKT (ME)
MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures
MUNI/A/0980/2009, interní kód MU
Name: Molekulární a supramolekulární stavební bloky pro nanostrukturované materiály (Acronym: MOSTNAMAT)
Investor: Masaryk University, Category A