Robust 1D open rack-like architecture in coordination polymers
of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and
[{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and
heterogeneous catalytic epoxidation of olefines

J 2010

Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines

DUTTA, D., A.D. JANA, M. DEBNATH, A. BHAUMIK, Jaromír MAREK et. al.

Basic information

Original name

Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines

Name in Czech

Robustní 1D koordinační architektura mezi koordinač. polymery Anderson. polyoxometalátů

Authors

DUTTA, D. (356 India), A.D. JANA (356 India), M. DEBNATH (356 India), A. BHAUMIK (356 India), Jaromír MAREK (203 Czech Republic, belonging to the institution) and Mahammad ALI (356 India, guarantor)

Edition

Dalton transactions : an international journal of inorganic chemistry, Cambridge, The Royal Society of Chemistry, 2010, 1477-9226

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 3.647

RIV identification code

RIV/00216224:14310/10:00047842

Organization unit

Faculty of Science

UT WoS

000284777500008

Keywords in English

ORGANIC-INORGANIC HYBRID; TRANSITION-METAL-COMPLEXES; RARE-EARTH CATIONS; CHAIN-LIKE POLYMER; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; KEGGIN POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; HETEROPOLY COMPOUNDS; MASS-SPECTROMETRY

Změněno: 2/5/2012 13:05, doc. RNDr. Jaromír Marek, Ph.D.

Abstract

ORIG CZ

V originále

Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organic complexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.

In Czech

Byly připraveny a difrakčně charakterizovány 2 nové hybridní organicko-anorganické sloučeniny [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} a [{Cu(en)(2)}(3){TeW6O24}] . 6H(2)O {en = ethyline-diamine} (2). Společným strukturním rysem obou sloučenin je unikátní jednodimenzionální koordinační struktura.

Links

MSM0021622415, plan (intention)

Name: Molekulární podstata buněčných a tkáňových regulací

Investor: Ministry of Education, Youth and Sports of the CR, Molecular basis of cell and tissue regulations

Citovat

DUTTA, D., A.D. JANA, M. DEBNATH, A. BHAUMIK, Jaromír MAREK and Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. Dalton transactions : an international journal of inorganic chemistry. Cambridge: The Royal Society of Chemistry, 2010, vol. 39, No 48, p. 11551-11559. ISSN 1477-9226.

@article{935619,
   author = {Dutta, D. and Jana, A.D. and Debnath, M. and Bhaumik, A. and Marek, Jaromír and Ali, Mahammad},
   article_location = {Cambridge},
   article_number = {48},
   keywords = {ORGANIC-INORGANIC HYBRID; TRANSITION-METAL-COMPLEXES; RARE-EARTH CATIONS; CHAIN-LIKE POLYMER; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; KEGGIN POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; HETEROPOLY COMPOUNDS; MASS-SPECTROMETRY},
   language = {eng},
   issn = {1477-9226},
   journal = {Dalton transactions : an international journal of inorganic chemistry},
   title = {Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines},
   url = {http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j},
   volume = {39},
   year = {2010}
}

TY  - JOUR
ID  - 935619
AU  - Dutta, D. - Jana, A.D. - Debnath, M. - Bhaumik, A. - Marek, Jaromír - Ali, Mahammad
PY  - 2010
TI  - Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
JF  - Dalton transactions : an international journal of inorganic chemistry
VL  - 39
IS  - 48
SP  - 11551-11559
EP  - 11551-11559
PB  - The Royal Society of Chemistry
SN  - 14779226
KW  - ORGANIC-INORGANIC HYBRID
KW  - TRANSITION-METAL-COMPLEXES
KW  - RARE-EARTH CATIONS
KW  - CHAIN-LIKE POLYMER
KW  - BUILDING-BLOCKS
KW  - CRYSTAL-STRUCTURE
KW  - KEGGIN POLYOXOMETALATE
KW  - HYDROTHERMAL SYNTHESIS
KW  - HETEROPOLY COMPOUNDS
KW  - MASS-SPECTROMETRY
UR  - http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j
N2  - Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organic complexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.
ER  -

DUTTA, D., A.D. JANA, M. DEBNATH, A. BHAUMIK, Jaromír MAREK and Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [$\{$Na-4(H2O)(14)$\}\{$Cu(gly)$\}$(2)][TeMo6O24] and [$\{$Cu(en)(2)$\}$(3)$\{$TeW6O24$\}$]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. \textit{Dalton transactions : an international journal of inorganic chemistry}. Cambridge: The Royal Society of Chemistry, 2010, vol.~39, No~48, p.~11551-11559. ISSN~1477-9226.

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