| DUTTA, D., A.D. JANA, M. DEBNATH, A. BHAUMIK, Jaromír MAREK and Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. Dalton transactions : an international journal of inorganic chemistry. Cambridge: The Royal Society of Chemistry, 2010, vol. 39, No 48, p. 11551-11559. ISSN 1477-9226. |
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@article{935619,
author = {Dutta, D. and Jana, A.D. and Debnath, M. and Bhaumik, A. and Marek, Jaromír and Ali, Mahammad},
article_location = {Cambridge},
article_number = {48},
keywords = {ORGANIC-INORGANIC HYBRID; TRANSITION-METAL-COMPLEXES; RARE-EARTH CATIONS; CHAIN-LIKE POLYMER; BUILDING-BLOCKS; CRYSTAL-STRUCTURE; KEGGIN POLYOXOMETALATE; HYDROTHERMAL SYNTHESIS; HETEROPOLY COMPOUNDS; MASS-SPECTROMETRY},
language = {eng},
issn = {1477-9226},
journal = {Dalton transactions : an international journal of inorganic chemistry},
title = {Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines},
url = {http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j},
volume = {39},
year = {2010}
}
TY - JOUR
ID - 935619
AU - Dutta, D. - Jana, A.D. - Debnath, M. - Bhaumik, A. - Marek, Jaromír - Ali, Mahammad
PY - 2010
TI - Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] and [{Cu(en)(2)}(3){TeW6O24}]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines
JF - Dalton transactions : an international journal of inorganic chemistry
VL - 39
IS - 48
SP - 11551-11559
EP - 11551-11559
PB - The Royal Society of Chemistry
SN - 14779226
KW - ORGANIC-INORGANIC HYBRID
KW - TRANSITION-METAL-COMPLEXES
KW - RARE-EARTH CATIONS
KW - CHAIN-LIKE POLYMER
KW - BUILDING-BLOCKS
KW - CRYSTAL-STRUCTURE
KW - KEGGIN POLYOXOMETALATE
KW - HYDROTHERMAL SYNTHESIS
KW - HETEROPOLY COMPOUNDS
KW - MASS-SPECTROMETRY
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2010/DT/c0dt00426j
N2 - Two novel organic-inorganic hybrid tungsto-and molybdo-telurates having formula [{Na-4(H2O)(14)}{Cu(gly)}(2)][TeMo6O24] (1){gly = glycine} and [{Cu(en)(2)}(3){TeW6O24}]center dot 6H(2)O {en = ethyline-diamine} (2) based on Anderson type heteropolyoxometalates (POMs) have been synthesized and characterized by X-ray crystallography. Common structural feature of both 1 and 2 is the presence of a unique 1D open rack-like architecture, where the disc shaped Anderson POMs act as steps and cationic Cu-organic complexes act as handles of the rack. In 1 the independent structural unit is a 1D coordination polymer with the above mentioned rack type architecture, while in 2, these independent rack-like architectures are further extended to a 2D coordination polymer. Heterogeneous catalysis for the epoxidation of cyclohexene and styrene by complexes 1 and 2 showed very good catalytic efficiency.
ER -
DUTTA, D., A.D. JANA, M. DEBNATH, A. BHAUMIK, Jaromír MAREK and Mahammad ALI. Robust 1D open rack-like architecture in coordination polymers of Anderson POMs [$\{$Na-4(H2O)(14)$\}\{$Cu(gly)$\}$(2)][TeMo6O24] and [$\{$Cu(en)(2)$\}$(3)$\{$TeW6O24$\}$]: synthesis, characterization and heterogeneous catalytic epoxidation of olefines. \textit{Dalton transactions : an international journal of inorganic chemistry}. Cambridge: The Royal Society of Chemistry, 2010, vol.~39, No~48, p.~11551-11559. ISSN~1477-9226.
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