SPÍCHAL, Zdeněk, Blanka VRBKOVÁ, Zdeněk MORAVEC, Jiří PINKAS and Marek NEČAS. Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands. Polyhedron. Velká Británie: Elsevier Science Ltd., 2011, vol. 30, No 9, p. 1620-1627. ISSN 0277-5387. |
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@article{936594, author = {Spíchal, Zdeněk and Vrbková, Blanka and Moravec, Zdeněk and Pinkas, Jiří and Nečas, Marek}, article_location = {Velká Británie}, article_number = {9}, keywords = {Diphosphine dioxide;Lanthanides;Coordination polymers;Chelates;X-ray crystallography}, language = {eng}, issn = {0277-5387}, journal = {Polyhedron}, title = {Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands}, url = {http://dx.doi.org/10.1016/j.poly.2011.03.027}, volume = {30}, year = {2011} }
TY - JOUR ID - 936594 AU - Spíchal, Zdeněk - Vrbková, Blanka - Moravec, Zdeněk - Pinkas, Jiří - Nečas, Marek PY - 2011 TI - Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands JF - Polyhedron VL - 30 IS - 9 SP - 1620-1627 EP - 1620-1627 PB - Elsevier Science Ltd. SN - 02775387 KW - Diphosphine dioxide;Lanthanides;Coordination polymers;Chelates;X-ray crystallography UR - http://dx.doi.org/10.1016/j.poly.2011.03.027 L2 - http://dx.doi.org/10.1016/j.poly.2011.03.027 N2 - Three large-bite diphosphine dioxide ligands were reacted with lanthanide salts to yield either molecular or polymeric complexes. The two flexible ligands gave bischelate complexes of general formulae [Ln(dppfO2)2Clx(NO3)2-x][FeCl4] and [Ln(dppdO2)2(NO3)2]NO3, where dppfO2 and dppdO2 are bis(diphenylphosphoryl) ferrocene and bis(diphenylphosphoryl)diphenyl ether, respectively. Reactions of the rigid bis(diphenylphosphoryl)benzene (dppbO2) with lanthanide salts yielded linear coordination polymers of a 1:1.5 metal-to-ligand stoichiometry. The compounds were studied by single crystal X-ray diffraction, IR spectroscopy, mass spectrometry, and TG/DSC techniques. ER -
SPÍCHAL, Zdeněk, Blanka VRBKOVÁ, Zdeněk MORAVEC, Jiří PINKAS and Marek NEČAS. Synthesis and structure of lanthanide complexes with large-bite diphosphine dioxide ligands. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2011, vol.~30, No~9, p.~1620-1627. ISSN~0277-5387.
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