| VÍCHA, Robert, Michal ROUCHAL, Zuzana KOZUBKOVÁ, Ivo KUŘITKA, Radek MAREK, Petra BRANNÁ a Richard ČMELÍK. Novel Adamantane-Bearing Anilines and Properties of Their Supramolecular Complexes with beta-Cyclodextrin. Supramolecular Chemistry. Taylor & Francis, roč. 23, č. 10, s. 663-677. ISSN 1061-0278. doi:10.1080/10610278.2011.593628. 2011. |
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@article{947544,
author = {Vícha, Robert and Rouchal, Michal and Kozubková, Zuzana and Kuřitka, Ivo and Marek, Radek and Branná, Petra and Čmelík, Richard},
article_number = {10},
doi = {http://dx.doi.org/10.1080/10610278.2011.593628},
keywords = {Adamantane; Amines; Cyclodextrins; Host-guest systems},
language = {eng},
issn = {1061-0278},
journal = {Supramolecular Chemistry},
title = {Novel Adamantane-Bearing Anilines and Properties of Their Supramolecular Complexes with beta-Cyclodextrin},
url = {http://dx.doi.org/10.1080/10610278.2011.593628},
volume = {23},
year = {2011}
}
TY - JOUR
ID - 947544
AU - Vícha, Robert - Rouchal, Michal - Kozubková, Zuzana - Kuřitka, Ivo - Marek, Radek - Branná, Petra - Čmelík, Richard
PY - 2011
TI - Novel Adamantane-Bearing Anilines and Properties of Their Supramolecular Complexes with beta-Cyclodextrin
JF - Supramolecular Chemistry
VL - 23
IS - 10
SP - 663-677
EP - 663-677
PB - Taylor & Francis
SN - 10610278
KW - Adamantane
KW - Amines
KW - Cyclodextrins
KW - Host-guest systems
UR - http://dx.doi.org/10.1080/10610278.2011.593628
L2 - http://dx.doi.org/10.1080/10610278.2011.593628
N2 - Several novel anilines bearing 1-adamantyl substituents that are useful for drug modification were synthesised from the corresponding 1-adamantyl (nitrophenyl) ketones. The host-guest systems of these prepared ligands with beta-cyclodextrin were studied using ESI-MS, NMR spectroscopy, titration calorimetry, and semi-empirical calculations. The complexes with 1:1 stoichiometry were found to predominantly exist as pseudorotaxane threaded structures with the adamantane cage sitting in the wider rim of beta-cyclodextrin. Such geometry was observed for all examined amines and is independent of their structure and/or presence of protic substituents.
ER -
VÍCHA, Robert, Michal ROUCHAL, Zuzana KOZUBKOVÁ, Ivo KUŘITKA, Radek MAREK, Petra BRANNÁ a Richard ČMELÍK. Novel Adamantane-Bearing Anilines and Properties of Their Supramolecular Complexes with beta-Cyclodextrin. \textit{Supramolecular Chemistry}. Taylor \&{} Francis, roč.~23, č.~10, s.~663-677. ISSN~1061-0278. doi:10.1080/10610278.2011.593628. 2011.
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