Other formats:
BibTeX
LaTeX
RIS
@proceedings{948694, author = {Moravec, Zdeněk and Nečas, Marek and Pinkas, Jiří}, booktitle = {2nd French-Czech Vltava chemistry meeting}, keywords = {aluminum chloride-alkoxides}, language = {eng}, isbn = {978-80-7395-412-3}, title = {Aluminum(III) chloride-alkoxides as molecular precursors for alumina}, url = {http://vltava.upce.cz/}, year = {2011} }
TY - CONF ID - 948694 AU - Moravec, Zdeněk - Nečas, Marek - Pinkas, Jiří PY - 2011 TI - Aluminum(III) chloride-alkoxides as molecular precursors for alumina SN - 9788073954123 KW - aluminum chloride-alkoxides UR - http://vltava.upce.cz/ N2 - The reactions of dichloroethylalane with selected alcohols and phenols afforded a series of six new crystalline aliminum(III) chloride-alkoxides which were structurally characterized by the single crystal X-ray diffraction analysis. The prepared molecules display, depending on the steric properties of employed substituents and the reaction and crystallization conditions, a large structural variability. These compounds are by virtue of their composition suitable single-source precursors for alumina. Therefore the transformations of aluminum(III) chloride-alkoxides to aluminum(III) oxide was performed by solution thermolysis in a high-boiling solvent. The reactions are based on alkylhalide elimination which was proved by indentifying byproducts by gas chromatography-mass spectrometry. ER -
MORAVEC, Zdeněk, Marek NEČAS and Jiří PINKAS. Aluminum(III) chloride-alkoxides as molecular precursors for alumina. In \textit{2nd French-Czech Vltava chemistry meeting}. 2011. ISBN~978-80-7395-412-3.
|