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@proceedings{948694,
author = {Moravec, Zdeněk and Nečas, Marek and Pinkas, Jiří},
booktitle = {2nd French-Czech Vltava chemistry meeting},
keywords = {aluminum chloride-alkoxides},
language = {eng},
isbn = {978-80-7395-412-3},
title = {Aluminum(III) chloride-alkoxides as molecular precursors for alumina},
url = {http://vltava.upce.cz/},
year = {2011}
}
TY - CONF
ID - 948694
AU - Moravec, Zdeněk - Nečas, Marek - Pinkas, Jiří
PY - 2011
TI - Aluminum(III) chloride-alkoxides as molecular precursors for alumina
SN - 9788073954123
KW - aluminum chloride-alkoxides
UR - http://vltava.upce.cz/
N2 - The reactions of dichloroethylalane with selected alcohols and phenols afforded a series of six new crystalline aliminum(III) chloride-alkoxides which were structurally characterized by the single crystal X-ray diffraction analysis. The prepared molecules display, depending on the steric properties of employed substituents and the reaction and crystallization conditions, a large structural variability. These compounds are by virtue of their composition suitable single-source precursors for alumina. Therefore the transformations of aluminum(III) chloride-alkoxides to aluminum(III) oxide was performed by solution thermolysis in a high-boiling solvent. The reactions are based on alkylhalide elimination which was proved by indentifying byproducts by gas chromatography-mass spectrometry.
ER -
MORAVEC, Zdeněk, Marek NEČAS and Jiří PINKAS. Aluminum(III) chloride-alkoxides as molecular precursors for alumina. In \textit{2nd French-Czech Vltava chemistry meeting}. 2011. ISBN~978-80-7395-412-3.
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