J 2011

Determination of aluminium in groundwater samples by GF-AAS, ICP-AES, ICP-MS and modelling of inorganic aluminium complexes

FRANKOWSKI, Marcin, Anetta ZIOLA-FRANKOWSKA, Iwona KURZYCA, Karel NOVOTNÝ, Tomáš VACULOVIČ et. al.

Basic information

Original name

Determination of aluminium in groundwater samples by GF-AAS, ICP-AES, ICP-MS and modelling of inorganic aluminium complexes

Name in Czech

Stanovení hliníku ve vzorcích podzemních vod pomocí GF-AAS, ICP-AES, ICP-MS a modelování anorganických hliníkových komplexů

Authors

FRANKOWSKI, Marcin (616 Poland), Anetta ZIOLA-FRANKOWSKA (616 Poland), Iwona KURZYCA (616 Poland), Karel NOVOTNÝ (203 Czech Republic, guarantor, belonging to the institution), Tomáš VACULOVIČ (203 Czech Republic, belonging to the institution), Viktor KANICKÝ (203 Czech Republic, belonging to the institution), Marcin SIEPAK (616 Poland) and Jerzy SIEPAK (616 Poland)

Edition

Environmental Monitoring and Assessment, 2011, 0167-6369

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.400

RIV identification code

RIV/00216224:14310/11:00054071

Organization unit

Faculty of Science

UT WoS

000295167500006

Keywords (in Czech)

hliník; podzemní voda; miocenní akvifer; komplexy hliníku; modelování; AAS; ICP

Keywords in English

aluminium; groundwater; miocene aquifer; aluminium complexes; modelling; AAS; ICP

Tags

Změněno: 8/2/2018 08:42, doc. Mgr. Karel Novotný, Ph.D.

Abstract

V originále

The paper presents the results of aluminium determinations in ground water samples of the Miocene aquifer from the area of the city of Poznan (Poland). The determined aluminium content amounted from < 0.0001 to 752.7 mu g L (-aEuro parts per thousand 1). The aluminium determinations were performed using three analytical techniques: graphite furnace atomic absorption spectrometry (GF-AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The results of aluminium determinations in groundwater samples for particular analytical techniques were compared. The results were used to identify the ascent of ground water from the Mesozoic aquifer to the Miocene aquifer in the area of the fault graben. Using the Mineql+ program, the modelling of the occurrence of aluminium and the following aluminium complexes: hydroxy, with fluorides and sulphates was performed. The paper presents the results of aluminium determinations in ground water using different analytical techniques as well as the chemical modelling in the Mineql+ program, which was performed for the first time and which enabled the identification of aluminium complexes in the investigated samples. The study confirms the occurrence of aluminium hydroxy complexes and aluminium fluoride complexes in the analysed groundwater samples. Despite the dominance of sulphates and organic matter in the sample, major participation of the complexes with these ligands was not stated based on the modelling.

In Czech

V článku jsou prezentovány výsledky stanovení hliníku ve vzorcích podzemních vod Miocenního akviferu z oblasti města Poznan (Polsko). Stanovení hliníku bylo provedeno s použitím tří technik: atomová absorpční spektrometrie s grafitovou kyvetou (GF-AAS), atomová emisní spektrometrie s indukčně vázaným plazmatem (ICP-AES) a hmotnostní spektrometrie s indukčně vázaným plazmatem (ICP-MS). Výsledky obdržené jednotlivými metodami byly porovnány. S využitím programu Mineq bylo povedeno modelování výskytu anorganických komplexů hliníku.