| MOHAMED, Walid Fathalla, Ibrahim A. I. ALI, Jaromír MAREK a Pavel PAZDERA. Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas. Online. Journal ofSulfur Chemistry. New York: Taylor & Francis, 2012, roč. 33, č. 1, s. 49-63. ISSN 1741-5993. Dostupné z: https://dx.doi.org/10.1080/17415993.2011.629094. [citováno 2024-04-24] |
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@article{968332,
author = {Mohamed, Walid Fathalla and Ali, Ibrahim A. I. and Marek, Jaromír and Pazdera, Pavel},
article_location = {New York},
article_number = {1},
doi = {http://dx.doi.org/10.1080/17415993.2011.629094},
keywords = {thiourea–isothiourea rearrangement; SNAr reaction; benzimidoyl thiourea; benzothiazole},
language = {eng},
issn = {1741-5993},
journal = {Journal ofSulfur Chemistry},
title = {Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas},
volume = {33},
year = {2012}
}
TY - JOUR
ID - 968332
AU - Mohamed, Walid Fathalla - Ali, Ibrahim A. I. - Marek, Jaromír - Pazdera, Pavel
PY - 2012
TI - Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas
JF - Journal ofSulfur Chemistry
VL - 33
IS - 1
SP - 49-63
EP - 49-63
PB - Taylor & Francis
SN - 17415993
KW - thiourea–isothiourea rearrangement
KW - SNAr reaction
KW - benzimidoyl thiourea
KW - benzothiazole
N2 - A series of new alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas 3a–h were prepared from benzamides 1a–c. Benzimidoyl thioureas 3a–e afforded 5-nitro-2-phenyl-benzothiazole 5a–c under basic conditions via thiourea–isothiourea rearrangement and SNAr. A mechanistic rationalization supported by the direct formation of benzothioamide 8 and bis-benzimidoyl sulfide 9 derivatives from the reaction of imidoyl isothiocyanate 2 with bulky amines was supported.
ER -
MOHAMED, Walid Fathalla, Ibrahim A. I. ALI, Jaromír MAREK a Pavel PAZDERA. Syntheses and reactivity of alkyl 1-[N-(2-chloro-5-nitro-phenyl)-benzimidoyl] thioureas. Online. \textit{Journal ofSulfur Chemistry}. New York: Taylor \&{} Francis, 2012, roč.~33, č.~1, s.~49-63. ISSN~1741-5993. Dostupné z: https://dx.doi.org/10.1080/17415993.2011.629094. [citováno 2024-04-24]
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