The diploma thesis deals with the synthesis of
bicyclo[1.1.1]pentane derivatives with different functional
groups in the bridgehead position for their further application
in reactions with 4,8,12-trioctyl-4,8,12-triazatriangulenium
(TATA) cation that represents a platform suitable for binding
of the resulting molecules to the surface. The connection of
the bicyclopentane cage to the platform has been successful in
the case when the ethynylene linker between the platform and
the cage bridgehead was used; the direct connection of the
later and the platform failed. The resulting molecules were
used for formation of self-assembled monolayers (SAMs) on the
gold surface (Au(111)). The thesis includes a review of
different types of SAM and their preparation and structures in
the literature part.