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@proceedings{1137246,
author = {Škoda, David and Stýskalík, Aleš and Moravec, Zdeněk and Pinkas, Jiří and Barnes, Craig},
booktitle = {21st International Conference on Materials and Technology},
keywords = {Titanosilicates epoxidation catalysis mesoporous},
language = {eng},
title = {Metallosilicates prepared by non-hydrolytic condensation reactions},
url = {http://icmt21.imt.si/en/home/},
year = {2013}
}
TY - CONF
ID - 1137246
AU - Škoda, David - Stýskalík, Aleš - Moravec, Zdeněk - Pinkas, Jiří - Barnes, Craig
PY - 2013
TI - Metallosilicates prepared by non-hydrolytic condensation reactions
KW - Titanosilicates epoxidation catalysis mesoporous
UR - http://icmt21.imt.si/en/home/
L2 - http://icmt21.imt.si/en/home/
N2 - Non-hydrolytic sol-gel reactions are efficient alternatives to classical aqueous techniques for synthesis of multimetallic oxides and inorganic-organic hybrid materials. We developed non-hydrolytic sol-gel routes to several groups of metallosilicate hybrid inorganic-organic materials based on polycondensation reactions. Titanosilicate xerogels were prepared by reactions between Ti(NEt2)4 or Ti(OR)4 , R = OiPr,OtBu and Si(OAc)4. These non-hydrolytic condensation reactions lead to form Si–O–Ti bonds and to release acetic acid ester and diethylacetamide as byproducts, respectively. Then the catalytic activity for epoxidation of cyclohexene was studied.
ER -
ŠKODA, David, Aleš STÝSKALÍK, Zdeněk MORAVEC, Jiří PINKAS a Craig BARNES. Metallosilicates prepared by non-hydrolytic condensation reactions. In \textit{21st International Conference on Materials and Technology}. 2013.
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