2013
Fast Classification of Brick Samples by Combination of Principal Component Analysis and Linear Discriminant Analysis Using Standoff Laser-Induced Breakdown Spectroscopy
VÍTKOVÁ, Gabriela; Lubomír PROKEŠ; Karel NOVOTNÝ; Aleš HRDLIČKA; Jan NOVOTNÝ et. al.Basic information
Original name
Fast Classification of Brick Samples by Combination of Principal Component Analysis and Linear Discriminant Analysis Using Standoff Laser-Induced Breakdown Spectroscopy
Authors
VÍTKOVÁ, Gabriela (203 Czech Republic, belonging to the institution); Lubomír PROKEŠ (203 Czech Republic, belonging to the institution); Karel NOVOTNÝ (203 Czech Republic, guarantor, belonging to the institution); Aleš HRDLIČKA (203 Czech Republic, belonging to the institution); Jan NOVOTNÝ (203 Czech Republic) and Jozef KAISER (203 Czech Republic)
Edition
Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy 2013, 2013
Other information
Language
English
Type of outcome
Conference abstract
Field of Study
10406 Analytical chemistry
Country of publisher
Italy
Confidentiality degree
is not subject to a state or trade secret
RIV identification code
RIV/00216224:14740/13:00070570
Organization unit
Central European Institute of Technology
Keywords in English
Stand-off LIBS; PCA; LDA; ANN; Geomaterials; Archeology
Changed: 14/2/2014 14:18, doc. Mgr. Karel Novotný, Ph.D.
Abstract
V originále
LDA is a multivariate statistical method for discrimination of objects up to a finite number of categories, based on a certain subset of all objects (training set). The principle of this method is maximizing the ratio of the between-class variance to the within-class variance. The decision rules obtained by classification of training set are later applied to the testing set. PCA was applied to reduce a dimensionality and the scores were computed from whole spectra (200 – 1000 nm) of 29 brick samples obtained by stand-off LIBS. After dividing the sample set into training and test samples first few principal components were used as inputs to LDA and the predictions of localities were computed. The results suggest that stand-off LIBS in combination with advanced statistical methods has a big potential for archaeological in-field measurements. By examining of PCA scores there was also discovered a dependence of firing temperature of bricks. Spectra of bricks fired on 300 – 1000 Celsius differs and this property is reflected significantly in only one of the principal components.
Links
ED1.1.00/02.0068, research and development project |
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