Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II)
Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor
Ligands

J 2014

Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands

JEREMIAS, Lukáš; Gabriel DEMO; Václav KUBÁT; Zdeněk TRÁVNÍČEK; Josef NOVOSAD et al.

Základní údaje

Originální název

Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands

Autoři

JEREMIAS, Lukáš; Gabriel DEMO; Václav KUBÁT; Zdeněk TRÁVNÍČEK a Josef NOVOSAD

Vydání

Phosphorus, Sulfur, and Silicon and the Related Elements, Taylor & Francis, 2014, 1042-6507

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.561

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/14:00075888

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Zinc(II) complexes Cadmium(II) complexes Xanthate Dithiophosphate X-ray diffraction

Štítky

AKR, podil, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 4. 2015 16:08, Ing. Andrea Mikešková

Anotace

V originále

A series of zinc(II) and cadmium(II) complexes, involving a combination of S-donor (xanthates and dithiophosphates) and N-donor (1,10-phen = 1,10-phenanthroline, 2,2-bipy = 2,2-bipyridine) ligands, of the composition [Cd(S2COnPr)2(2,2-bipy)] (1), [Cd(S2COnPr)2(1,10-phen)] (2), [Cd(S2P(OEt)2)2(2,2-bipy)] (3), [Cd(S2P(OEt)2)2(1,10-phen)] (4), [Zn(S2COnPr)2(2,2-bipy)] (5), [Zn(S2COnPr)2(1,10-phen)] (6), [Zn(S2P(OEt)2)2(2,2-bipy)] (7) and [Zn(S2P(OEt)2)2(1,10-phen)] (8) was prepared. The complexes (1–8) were characterized by elemental analysis and single-crystal X-ray analysis. X-ray structures revealed that the coordination geometries vary from octahedral (complexes 1–4), through square-pyramidal (complexes 5–6) to tetrahedral (complexes 7–8), depending on a combination of the central metal atoms and the corresponding S-donor and N-donor ligands. Similarities and discrepancies among the individual molecular structures as well as non-covalent contacts stabilizing crystal structures are discussed in more detail.

Přiložené soubory

pssi_final_pdf.pdf

Požádat o autorskou verzi souboru

Citovat

JEREMIAS, Lukáš; Gabriel DEMO; Václav KUBÁT; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands. Phosphorus, Sulfur, and Silicon and the Related Elements. Taylor & Francis, 2014, roč. 189, č. 10, s. 1475-1488. ISSN 1042-6507. Dostupné z: https://doi.org/10.1080/10426507.2014.902825.

@article{1188085,
   author = {Jeremias, Lukáš and Demo, Gabriel and Kubát, Václav and Trávníček, Zdeněk and Novosad, Josef},
   article_number = {10},
   doi = {https://doi.org/10.1080/10426507.2014.902825},
   keywords = {Zinc(II) complexes Cadmium(II) complexes Xanthate Dithiophosphate X-ray diffraction},
   language = {eng},
   issn = {1042-6507},
   journal = {Phosphorus, Sulfur, and Silicon and the Related Elements},
   title = {Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands},
   volume = {189},
   year = {2014}
}

TY  - JOUR
ID  - 1188085
AU  - Jeremias, Lukáš - Demo, Gabriel - Kubát, Václav - Trávníček, Zdeněk - Novosad, Josef
PY  - 2014
TI  - Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands
JF  - Phosphorus, Sulfur, and Silicon and the Related Elements
VL  - 189
IS  - 10
SP  - 1475-1488
EP  - 1475-1488
PB  - Taylor & Francis
SN  - 10426507
KW  - Zinc(II) complexes Cadmium(II) complexes Xanthate Dithiophosphate X-ray diffraction
N2  - A series of zinc(II) and cadmium(II) complexes, involving a combination of S-donor (xanthates and dithiophosphates) and N-donor (1,10-phen = 1,10-phenanthroline, 2,2-bipy = 2,2-bipyridine) ligands, of the composition [Cd(S2COnPr)2(2,2-bipy)] (1), [Cd(S2COnPr)2(1,10-phen)] (2), [Cd(S2P(OEt)2)2(2,2-bipy)] (3), [Cd(S2P(OEt)2)2(1,10-phen)] (4), [Zn(S2COnPr)2(2,2-bipy)] (5), [Zn(S2COnPr)2(1,10-phen)] (6), [Zn(S2P(OEt)2)2(2,2-bipy)] (7) and [Zn(S2P(OEt)2)2(1,10-phen)] (8) was prepared. The complexes (1–8) were characterized by elemental analysis and single-crystal X-ray analysis. X-ray structures revealed that the coordination geometries vary from octahedral (complexes 1–4), through square-pyramidal (complexes 5–6) to tetrahedral (complexes 7–8), depending on a combination of the central metal atoms and the corresponding S-donor and N-donor ligands. Similarities and discrepancies among the individual molecular structures as well as non-covalent contacts stabilizing crystal structures are discussed in more detail.
ER  -

JEREMIAS, Lukáš; Gabriel DEMO; Václav KUBÁT; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. Synthesis and X-Ray Structures of Zinc(II) and Cadmium(II) Heteroleptic Complexes Involving 1,1-Dithiolate and N-Donor Ligands. \textit{Phosphorus, Sulfur, and Silicon and the Related Elements}. Taylor \&{} Francis, 2014, roč.~189, č.~10, s.~1475-1488. ISSN~1042-6507. Dostupné z: https://doi.org/10.1080/10426507.2014.902825.

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