X-ray structures of heteroleptic zinc(II) complexes involving
combinations of O,O-dialkyldithiophosphato and bidentate
N-donor ligands

J 2014

X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

JEREMIAS, Lukáš; Gabriel DEMO; Michal BABIAK; Jan VÍCHA; Zdeněk TRÁVNÍČEK et al.

Základní údaje

Originální název

X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands

Autoři

JEREMIAS, Lukáš; Gabriel DEMO; Michal BABIAK; Jan VÍCHA; Zdeněk TRÁVNÍČEK a Josef NOVOSAD

Vydání

Zeitschrift für Kristallographie - Crystalline Materials, DE GRUYTER, 2014, 0044-2968

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.310

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/14:00075889

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction

Štítky

AKR, podil, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 4. 2015 18:33, Ing. Andrea Mikešková

Anotace

V originále

The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi–pi stacking interactions and/or C–H···S non-covalent contacts

Přiložené soubory

zkri-2014-1736_final.pdf

Požádat o autorskou verzi souboru

Citovat

JEREMIAS, Lukáš; Gabriel DEMO; Michal BABIAK; Jan VÍCHA; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands. Zeitschrift für Kristallographie - Crystalline Materials. DE GRUYTER, 2014, roč. 229, č. 7, s. 537-542. ISSN 0044-2968. Dostupné z: https://doi.org/10.1515/zkri-2014-1736.

@article{1188086,
   author = {Jeremias, Lukáš and Demo, Gabriel and Babiak, Michal and Vícha, Jan and Trávníček, Zdeněk and Novosad, Josef},
   article_number = {7},
   doi = {https://doi.org/10.1515/zkri-2014-1736},
   keywords = {1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction},
   language = {eng},
   issn = {0044-2968},
   journal = {Zeitschrift für Kristallographie - Crystalline Materials},
   title = {X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands},
   volume = {229},
   year = {2014}
}

TY  - JOUR
ID  - 1188086
AU  - Jeremias, Lukáš - Demo, Gabriel - Babiak, Michal - Vícha, Jan - Trávníček, Zdeněk - Novosad, Josef
PY  - 2014
TI  - X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands
JF  - Zeitschrift für Kristallographie - Crystalline Materials
VL  - 229
IS  - 7
SP  - 537-542
EP  - 537-542
PB  - DE GRUYTER
SN  - 00442968
KW  - 1 1-dithiolate dithiophosphate zinc(II) complexes crystal structure analysis X-ray diffraction
N2  - The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via pi–pi stacking interactions and/or C–H···S non-covalent contacts
ER  -

JEREMIAS, Lukáš; Gabriel DEMO; Michal BABIAK; Jan VÍCHA; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O-dialkyldithiophosphato and bidentate N-donor ligands. \textit{Zeitschrift für Kristallographie - Crystalline Materials}. DE GRUYTER, 2014, roč.~229, č.~7, s.~537-542. ISSN~0044-2968. Dostupné z: https://doi.org/10.1515/zkri-2014-1736.

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