Construction of Larger Molecular Aluminophosphate Cages from
the Cyclic Four-Ring Building Unit

J 2014

Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR, Jiří PINKAS et. al.

Základní údaje

Originální název

Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit

Autoři

CHYBA, Jan (203 Česká republika, domácí), Zdeněk MORAVEC (203 Česká republika, domácí), Marek NEČAS (203 Česká republika, domácí), Sanjay MATHUR (276 Německo) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

Inorganic Chemistry, Spojené státy americké, American Chemical Society, Washington DC, 2014, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.762

Kód RIV

RIV/00216224:14740/14:00075992

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1021/ic500083a

UT WoS

000334092500062

Klíčová slova anglicky

aluminophosphates; bis(trimethysiloxy)phosphoric acid; secondary building units

Štítky

kontrola MP, podil, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 3. 2018 10:20, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

New molecular aluminophosphates of different nuclearity are synthesized by a stepwise process and structurally characterized. The alkane elimination reaction of bis(trimethysiloxy)phosphoric acid, OP(OH)(OSiMe3)2, with trialkylalanes, AlR3 (R = Me, Et, iBu), provides the cyclic dimeric aluminophosphates, [(AlR2{m2-O2P(OSiMe3)2})2] (R = Me (1), Et (2), iBu (3)). Unsymmetrically substituted cyclic aluminophosphonate [(AlMe2{m2-O2P(OSiMe3)(cHex)})2] (cis/trans 4), is prepared by dealkylsilylation reaction of cHexP(O)(OSiMe3)2 with AlMe3. The molecules 1-4 containing the [Al2(m2-O2P)2] inorganic core are structural and spectroscopic models for the single four-ring (S4R) secondary building units (SBU) of zeolite frameworks. Compound 1 serves as a starting point in construction of larger molecular units by reactions with OP(OH)(OSiMe3)2 as a cage-extending reagent, and with diketones, such as Hhfacac (1,1,1,5,5,5-hexafluoropentan-2,4-dione) and Hacac (pentan-2,4-dione), as capping reagents. The reaction of 1 with four eq. of Hhfacac lead to new cyclic aluminophosphate [(Al(hfacac)2{m2-O2P(OSiMe3)2})2] (5), existing in two isomeric (D2 and C2h) forms. The reaction of 1 with two eq. of OP(OH)(OSiMe3)2 and one eq. of Hhfacac provides a molecular aluminophosphate [AlMe{Al(hfacac)}2{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}2{OP(OSiMe3)3}] (6) while by adding first the Hhfacac and using three eq. of OP(OH)(OSiMe3)2, we isolate [Al{Al(hfacac)}2{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}2H{OP(O)(OSiMe3)2}2] (7). These molecules contain units in their cores that imitate 4=1 SBU of zeolite frameworks. The reaction with the order of component mixing 1, Hhfacac, OP(OH)(OSiMe3)2 at the 1:2:2 molar ratio lead to the formation of a larger cluster [(Al(AlMe){Al(hfacac)}{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}3)2] (8) containing both S4R and 4=1 structural units. Similarly, Hacac (pentan-2,4-dione) provides an isostructural [(Al(AlMe){Al(acac)}{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}3)2] (9).

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

EE2.3.30.0037, projekt VaV

Název: Zaměstnáním nejlepších mladých vědců k rozvoji mezinárodní spolupráce

7AMB13DE006, projekt VaV

Název: Chemické syntézy nano-fosforečnanů kovů pomocí mikrovlných, sonochemických a elektrospinningových metod (Akronym: SYNPHOSO)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Chemické syntézy nano-fosforečnanů kovů pomocí mikrovlnných, sonochemických a elektrospinningových metod

Citovat

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR a Jiří PINKAS. Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit. Inorganic Chemistry. Spojené státy americké: American Chemical Society, Washington DC, 2014, roč. 53, č. 7, s. 3753-3762. ISSN 0020-1669. Dostupné z: https://dx.doi.org/10.1021/ic500083a.

@article{1192623,
   author = {Chyba, Jan and Moravec, Zdeněk and Nečas, Marek and Mathur, Sanjay and Pinkas, Jiří},
   article_location = {Spojené státy americké},
   article_number = {7},
   doi = {http://dx.doi.org/10.1021/ic500083a},
   keywords = {aluminophosphates; bis(trimethysiloxy)phosphoric acid; secondary building units},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorganic Chemistry},
   title = {Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit},
   url = {http://www.ncbi.nlm.nih.gov/pubmed/24617956},
   volume = {53},
   year = {2014}
}

TY  - JOUR
ID  - 1192623
AU  - Chyba, Jan - Moravec, Zdeněk - Nečas, Marek - Mathur, Sanjay - Pinkas, Jiří
PY  - 2014
TI  - Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit
JF  - Inorganic Chemistry
VL  - 53
IS  - 7
SP  - 3753-3762
EP  - 3753-3762
PB  - American Chemical Society, Washington DC
SN  - 00201669
KW  - aluminophosphates
KW  - bis(trimethysiloxy)phosphoric acid
KW  - secondary building units
UR  - http://www.ncbi.nlm.nih.gov/pubmed/24617956
L2  - http://www.ncbi.nlm.nih.gov/pubmed/24617956
N2  - New molecular aluminophosphates of different nuclearity are synthesized by a stepwise process and structurally characterized. The alkane elimination reaction of bis(trimethysiloxy)phosphoric acid, OP(OH)(OSiMe3)2, with trialkylalanes, AlR3 (R = Me, Et, iBu), provides the cyclic dimeric aluminophosphates, [(AlR2{m2-O2P(OSiMe3)2})2] (R = Me (1), Et (2), iBu (3)). Unsymmetrically substituted cyclic aluminophosphonate [(AlMe2{m2-O2P(OSiMe3)(cHex)})2] (cis/trans 4), is prepared by dealkylsilylation reaction of cHexP(O)(OSiMe3)2 with AlMe3. The molecules 1-4 containing the [Al2(m2-O2P)2] inorganic core are structural and spectroscopic models for the single four-ring (S4R) secondary building units (SBU) of zeolite frameworks. Compound 1 serves as a starting point in construction of larger molecular units by reactions with OP(OH)(OSiMe3)2 as a cage-extending reagent, and with diketones, such as Hhfacac (1,1,1,5,5,5-hexafluoropentan-2,4-dione) and Hacac (pentan-2,4-dione), as capping reagents. The reaction of 1 with four eq. of Hhfacac lead to new cyclic aluminophosphate [(Al(hfacac)2{m2-O2P(OSiMe3)2})2] (5), existing in two isomeric (D2 and C2h) forms. The reaction of 1 with two eq. of OP(OH)(OSiMe3)2 and one eq. of Hhfacac provides a molecular aluminophosphate [AlMe{Al(hfacac)}2{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}2{OP(OSiMe3)3}] (6) while by adding first the Hhfacac and using three eq. of OP(OH)(OSiMe3)2, we isolate [Al{Al(hfacac)}2{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}2H{OP(O)(OSiMe3)2}2] (7). These molecules contain units in their cores that imitate 4=1 SBU of zeolite frameworks. The reaction with the order of component mixing 1, Hhfacac, OP(OH)(OSiMe3)2 at the 1:2:2 molar ratio lead to the formation of a larger cluster [(Al(AlMe){Al(hfacac)}{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}3)2] (8) containing both S4R and 4=1 structural units. Similarly, Hacac (pentan-2,4-dione) provides an isostructural [(Al(AlMe){Al(acac)}{m3-O3P(OSiMe3)}2{m2-O2P(OSiMe3)2}3)2] (9).
ER  -

CHYBA, Jan, Zdeněk MORAVEC, Marek NEČAS, Sanjay MATHUR a Jiří PINKAS. Construction of Larger Molecular Aluminophosphate Cages from the Cyclic Four-Ring Building Unit. \textit{Inorganic Chemistry}. Spojené státy americké: American Chemical Society, Washington DC, 2014, roč.~53, č.~7, s.~3753-3762. ISSN~0020-1669. Dostupné z: https://dx.doi.org/10.1021/ic500083a.

Podrobný výpis o publikaci