PREPARATION OF NEW COORDINATION   COMPOUNDS OF
(1-AMINO-1-METHYL-ETHYL)  PHOSPHONIC ACID WITH SOME d-METALS  
AND URANYL ION

a 2014

PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION

DOROSHENKO, Iaroslav, Michal BABIAK a Jiří PINKAS

Základní údaje

Originální název

PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION

Autoři

DOROSHENKO, Iaroslav (804 Ukrajina, domácí), Michal BABIAK (703 Slovensko, domácí) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

66. sjezd chemických společností. Ostrava. Česka republika. 2014

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 0.272

Kód RIV

RIV/00216224:14740/14:00073851

Organizační jednotka

Středoevropský technologický institut

ISSN

Klíčová slova česky

Koordinacni clouceniny; fosfonaty; fosfonova kyselina;

Klíčová slova anglicky

Coordination compounds; Phosphonates; phosphonic acid;

Změněno: 1. 12. 2014 01:21, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

GAP207/11/0555, projekt VaV

Název: Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti (Akronym: OPNW)

Investor: Grantová agentura ČR, Oxidy a fosforečnany kovů jako formy jaderného odpadu: studium sonochemického srážení, tepelných přeměn a rozpustnosti

Citovat

DOROSHENKO, Iaroslav, Michal BABIAK a Jiří PINKAS. PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION. In 66. sjezd chemických společností. Ostrava. Česka republika. 2014. ISSN 0009-2770.

@proceedings{1197347,
   author = {Doroshenko, Iaroslav and Babiak, Michal and Pinkas, Jiří},
   booktitle = {66. sjezd chemických společností. Ostrava. Česka republika.},
   keywords = {Coordination compounds; Phosphonates; phosphonic acid;},
   language = {eng},
   title = {PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION},
   year = {2014}
}

TY  - CONF
ID  - 1197347
AU  - Doroshenko, Iaroslav - Babiak, Michal - Pinkas, Jiří
PY  - 2014
TI  - PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION
KW  - Coordination compounds
KW  - Phosphonates
KW  - phosphonic acid;
N2  - Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+
ER  -

DOROSHENKO, Iaroslav, Michal BABIAK a Jiří PINKAS. PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION. In \textit{66. sjezd chemických společností. Ostrava. Česka republika.}. 2014. ISSN~0009-2770.

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