| CIVIŠ, Svatopluk, Martin FERUS, Judit ŠPONEROVÁ, Jiří ŠPONER, Ladislav KAVAN and Markéta ZUKALOVÁ. Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface. Chemical Communications. Cambridge: Royal Society of Chemistry, 2014, vol. 50, No 57, p. 7712-7715. ISSN 1359-7345. Available from: https://dx.doi.org/10.1039/c4cc01992j. |
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@article{1202581,
author = {Civiš, Svatopluk and Ferus, Martin and Šponerová, Judit and Šponer, Jiří and Kavan, Ladislav and Zukalová, Markéta},
article_location = {Cambridge},
article_number = {57},
doi = {http://dx.doi.org/10.1039/c4cc01992j},
keywords = {TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR},
language = {eng},
issn = {1359-7345},
journal = {Chemical Communications},
title = {Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface},
url = {http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract},
volume = {50},
year = {2014}
}
TY - JOUR
ID - 1202581
AU - Civiš, Svatopluk - Ferus, Martin - Šponerová, Judit - Šponer, Jiří - Kavan, Ladislav - Zukalová, Markéta
PY - 2014
TI - Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
JF - Chemical Communications
VL - 50
IS - 57
SP - 7712-7715
EP - 7712-7715
PB - Royal Society of Chemistry
SN - 13597345
KW - TITANIUM-DIOXIDE
KW - OXYGEN-EXCHANGE
KW - CARBON-MONOXIDE
KW - HYDROCARBONS
KW - CHEMISTRY
KW - TIO2(101)
KW - OXIDATION
KW - ISOTOPE
KW - METAL
KW - FTIR
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract
L2 - http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract
N2 - High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules.
ER -
CIVIŠ, Svatopluk, Martin FERUS, Judit ŠPONEROVÁ, Jiří ŠPONER, Ladislav KAVAN and Markéta ZUKALOVÁ. Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface. \textit{Chemical Communications}. Cambridge: Royal Society of Chemistry, 2014, vol.~50, No~57, p.~7712-7715. ISSN~1359-7345. Available from: https://dx.doi.org/10.1039/c4cc01992j.
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