Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new
member of the lindackerite supergroup from Jachymov, Czech
Republic

J 2014

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN et. al.

Základní údaje

Originální název

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic

Autoři

PLÁŠIL, Jakub (203 Česká republika, garant), Jiří SEJKORA (203 Česká republika), Radek ŠKODA (203 Česká republika, domácí), Milan NOVÁK (203 Česká republika, domácí), Anatoly V KASATKIN (643 Rusko), Pavel ŠKACHA (203 Česká republika), František VESELOVSKY (203 Česká republika), Kristýna FEJFAROVÁ (203 Česká republika) a Petr ONDRUŠ (203 Česká republika)

Vydání

Mineralogical Magazine, London, Mineralogical Society, 2014, 0026-461X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10500 1.5. Earth and related environmental sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.026

Kód RIV

RIV/00216224:14310/14:00079323

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1180/minmag.2014.078.5.16

UT WoS

000348531400016

Klíčová slova anglicky

hloušekite; new mineral; arsenate; lindackerite supergroup; lindackerite group; ondrusite group; crystal structure

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 8. 4. 2015 15:25, Ing. Andrea Mikešková

Anotace

V originále

Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), is a new supergene arsenate mineral from the Geister vein (Rovnost mine), Jachymov (St Joachimsthal), Western Bohemia, Czech Republic. It was found along with veselovskyite, pradetite, lavendulan, arsenolite, babanekite and gypsum on the surface of strongly altered ore fragments containing dominant tennantite and chalcopyrite. Hlous. ekite forms thin, lath-like crystals, locally elongated reaching up to 3 mm across. It is transparent, has a pale green colour with vitreous lustre, has a greyish-white streak and it is very brittle with an uneven fracture. It does not fluoresce under shortwave or longwave ultraviolet radiation. Cleavage on {010} is perfect; the Mohs hardness is 2-3. The calculated density is 3.295 g cm(-3). Hlous. ekite is optically biaxial with alpha' = 1.653(2) and gamma' = 1.73. The estimated optical orientation is gamma' vs. elongation (c) = 14(1)degrees. In larger grains it is weakly to moderately pleochroic (alpha = colourless, gamma = pale green to green). Hlousekite is triclinic, space group P (1) over bar, a = 6.4010(6), b = 8.0041(6), c = 10.3969(14) angstrom, alpha = 85.824(8), beta = 79.873(9), gamma = 84.655(7)degrees and V = 521.23(10) angstrom(3), with Z = 1, a:b:c = 0.800: 1: 1.299. The eight strongest lines in the powder X-ray diffraction (XRD) pattern [ d in angstrom (I)(hkl)] are 10.211(100)(001), 7.974(9)(010), 3.984(6)(020), 3.656(5)(1 (1) over bar2), 3.631(5)(0 (2) over bar1), 3.241(5)(022), 3.145(5)(200) and 3.006(5)(210). Chemical analysis by electron microprobe yielded MgO 0.20, FeO 0.10, NiO 5.79, CoO 1.80, CuO 29.53, ZnO 0.66, Al2O3 0.14, P2O5 0.11, As2O5 45.01, H2O 17.71 (calc.), for a total of 101.05 wt.%. The resulting empirical formula, calculated by stoichiometry (9H(2)O + 2OH), obtained from the crystal structure, is (Ni0.79Co0.25)(Sigma 1.04)(Cu3.78Zn0.08Mg0.05Al0.03Fe0.01)(Sigma 3.95) (AsO4)(1. 98)(PO4)(0.02)(AsO3OH)(2.00)(H2O)(9.00). The ideal endmember formula, NiCu4(AsO4)(2)(AsO3OH)(2)(H2O)(9.00), requires NiO 7.23, CuO 30.81, As2O5 44.51, H2O 17.45, total 100.00 wt.%. The crystal structure of hlous. ekite was solved by charge flipping from single-crystal XRD data and refined to R-1 = 0.0599 for 1441 reflections with [I-obs > 3 sigma(I)]. Hlousekite is a new member of the lindackerite group (also including lindackerite, pradetite and veselovskyite) of the lindackerite supergroup. The ondrusite group of the lindackerite supergroup includes ondrus. ite, chudobaite, geigerite and klajite. The establishment of these two groups reflects the difference between the crystal structures of their members, mainly in the coordination environment of the Me cations.

Citovat

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN, Pavel ŠKACHA, František VESELOVSKY, Kristýna FEJFAROVÁ a Petr ONDRUŠ. Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic. Mineralogical Magazine. London: Mineralogical Society, 2014, roč. 78, č. 5, s. 1341-1353. ISSN 0026-461X. Dostupné z: https://dx.doi.org/10.1180/minmag.2014.078.5.16.

@article{1228834,
   author = {Plášil, Jakub and Sejkora, Jiří and Škoda, Radek and Novák, Milan and Kasatkin, Anatoly V and Škacha, Pavel and Veselovsky, František and Fejfarová, Kristýna and Ondruš, Petr},
   article_location = {London},
   article_number = {5},
   doi = {http://dx.doi.org/10.1180/minmag.2014.078.5.16},
   keywords = {hloušekite; new mineral; arsenate; lindackerite supergroup; lindackerite group; ondrusite group; crystal structure},
   language = {eng},
   issn = {0026-461X},
   journal = {Mineralogical Magazine},
   title = {Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic},
   volume = {78},
   year = {2014}
}

TY  - JOUR
ID  - 1228834
AU  - Plášil, Jakub - Sejkora, Jiří - Škoda, Radek - Novák, Milan - Kasatkin, Anatoly V - Škacha, Pavel - Veselovsky, František - Fejfarová, Kristýna - Ondruš, Petr
PY  - 2014
TI  - Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic
JF  - Mineralogical Magazine
VL  - 78
IS  - 5
SP  - 1341-1353
EP  - 1341-1353
PB  - Mineralogical Society
SN  - 0026461X
KW  - hloušekite
KW  - new mineral
KW  - arsenate
KW  - lindackerite supergroup
KW  - lindackerite group
KW  - ondrusite group
KW  - crystal structure
N2  - Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), is a new supergene arsenate mineral from the Geister vein (Rovnost mine), Jachymov (St Joachimsthal), Western Bohemia, Czech Republic. It was found along with veselovskyite, pradetite, lavendulan, arsenolite, babanekite and gypsum on the surface of strongly altered ore fragments containing dominant tennantite and chalcopyrite. Hlous. ekite forms thin, lath-like crystals, locally elongated reaching up to 3 mm across. It is transparent, has a pale green colour with vitreous lustre, has a greyish-white streak and it is very brittle with an uneven fracture. It does not fluoresce under shortwave or longwave ultraviolet radiation. Cleavage on {010} is perfect; the Mohs hardness is 2-3. The calculated density is 3.295 g cm(-3). Hlous. ekite is optically biaxial with alpha' = 1.653(2) and gamma' = 1.73. The estimated optical orientation is gamma' vs. elongation (c) = 14(1)degrees. In larger grains it is weakly to moderately pleochroic (alpha = colourless, gamma = pale green to green). Hlousekite is triclinic, space group P (1) over bar, a = 6.4010(6), b = 8.0041(6), c = 10.3969(14) angstrom, alpha = 85.824(8), beta = 79.873(9), gamma = 84.655(7)degrees and V = 521.23(10) angstrom(3), with Z = 1, a:b:c = 0.800: 1: 1.299. The eight strongest lines in the powder X-ray diffraction (XRD) pattern [ d in angstrom (I)(hkl)] are 10.211(100)(001), 7.974(9)(010), 3.984(6)(020), 3.656(5)(1 (1) over bar2), 3.631(5)(0 (2) over bar1), 3.241(5)(022), 3.145(5)(200) and 3.006(5)(210). Chemical analysis by electron microprobe yielded MgO 0.20, FeO 0.10, NiO 5.79, CoO 1.80, CuO 29.53, ZnO 0.66, Al2O3 0.14, P2O5 0.11, As2O5 45.01, H2O 17.71 (calc.), for a total of 101.05 wt.%. The resulting empirical formula, calculated by stoichiometry (9H(2)O + 2OH), obtained from the crystal structure, is (Ni0.79Co0.25)(Sigma 1.04)(Cu3.78Zn0.08Mg0.05Al0.03Fe0.01)(Sigma 3.95) (AsO4)(1. 98)(PO4)(0.02)(AsO3OH)(2.00)(H2O)(9.00). The ideal endmember formula, NiCu4(AsO4)(2)(AsO3OH)(2)(H2O)(9.00), requires NiO 7.23, CuO 30.81, As2O5 44.51, H2O 17.45, total 100.00 wt.%. The crystal structure of hlous. ekite was solved by charge flipping from single-crystal XRD data and refined to R-1 = 0.0599 for 1441 reflections with [I-obs > 3 sigma(I)]. Hlousekite is a new member of the lindackerite group (also including lindackerite, pradetite and veselovskyite) of the lindackerite supergroup. The ondrusite group of the lindackerite supergroup includes ondrus. ite, chudobaite, geigerite and klajite. The establishment of these two groups reflects the difference between the crystal structures of their members, mainly in the coordination environment of the Me cations.
ER  -

PLÁŠIL, Jakub, Jiří SEJKORA, Radek ŠKODA, Milan NOVÁK, Anatoly V KASATKIN, Pavel ŠKACHA, František VESELOVSKY, Kristýna FEJFAROVÁ a Petr ONDRUŠ. Hloušekite, (Ni,Co)Cu-4(AsO4)(2)(AsO3OH)(2)(H2O)(9), a new member of the lindackerite supergroup from Jachymov, Czech Republic. \textit{Mineralogical Magazine}. London: Mineralogical Society, 2014, roč.~78, č.~5, s.~1341-1353. ISSN~0026-461X. Dostupné z: https://dx.doi.org/10.1180/minmag.2014.078.5.16.

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