J 2014

Mineral assemblages, comositional variation, and crystal structure of feruvitic tourmaline from a contaminated anatectic pegmatite at Mirošov near Strážek, Moldanubian Zone, Czech Republic

GADAS, Petr, Milan NOVÁK, Jan CEMPÍREK, Jan FILIP, Michaela VAŠINOVÁ GALIOVÁ et. al.

Basic information

Original name

Mineral assemblages, comositional variation, and crystal structure of feruvitic tourmaline from a contaminated anatectic pegmatite at Mirošov near Strážek, Moldanubian Zone, Czech Republic

Name in Czech

Minerální asociace, změny ve složení a krystalová struktura feruvitického turmalínu z kontaminovaného pegmatitu z Mirošova u Strážku, moldanubikum, Česká republika

Authors

GADAS, Petr (203 Czech Republic, guarantor, belonging to the institution), Milan NOVÁK (203 Czech Republic, belonging to the institution), Jan CEMPÍREK (203 Czech Republic), Jan FILIP (203 Czech Republic), Michaela VAŠINOVÁ GALIOVÁ (203 Czech Republic, belonging to the institution), Lee GROAT (124 Canada) and Dalibor VŠIANSKÝ (203 Czech Republic, belonging to the institution)

Edition

Canadian Mineralogist, Mineralogical Association of Canada. 2014, 0008-4476

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10500 1.5. Earth and related environmental sciences

Country of publisher

Canada

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.181

RIV identification code

RIV/00216224:14310/14:00074471

Organization unit

Faculty of Science

UT WoS

000339701800010

Keywords (in Czech)

feruvit; skoryl; EMPA; LA-ICP-MS; Mossbauerova spektroskopie; prášková a single crystal RTG; granitický pegmatit; kontaminace; moldanubikum, Česká republika

Keywords in English

feruvite; schorl; EMPA; LA-ICP-MS; Mossbauer spectroscopy; powder and single crystal XRD; granitic pegmatite; contamination; Moldanubian Zone; Czech Republic

Tags

International impact, Reviewed
Změněno: 28/4/2015 09:54, Ing. Andrea Mikešková

Abstract

V originále

Amphibole-bearing, simply zoned, anatectic pegmatite, up to 20 cm thick, cuts calc-silicate rocks at Mirogov, near Strazek, in the Moldanubian Zone of the Czech Republic. Common amphibole (K-rich magnesio-hornblende to ferro-hastingsite), plagioclase An(30-42) and titanite, along with accessory feruvitic tourmaline-Ca-rich schorl to Na-rich feruvite-are indicators of Ca and Fe-contamination from the host rock. Interstitial tourmaline from the outer unit (TU1) and tourmaline from graphic intergrowths with quartz in more evolved parts of the pegmatite (TU2) have similar chemical compositions (EMPA, LA-ICP-MS) with Ca = 0.37-0.58 apfu, Al = 4.77-5.77 apfu; TU1 has higher Mg/(Mg + Fe-tot) = 0.52-0.41 compared to TU2 (0.39-0.15). TU1 is enriched in Ti, V, Cr, Sr, and TU2 in Li and Zn, respectively. Late microscopic veinlets of Na,Al,Mg-enriched tourmaline (TU3)-Ca-rich dravite/schorl-replace both TU1 and TU2. A combination of EMPA, single crystal XRD data, and bond-valence optimization applied to the TU2 data yielded the formula (x)(Ca-0 Na-494(0.451)square(0.055)) (Y)(Mg-0 Al-422(0) 365Fe1.1432+Fe0.9523+Mn0 (029) Ti0.084Zn0.005) (Z)(Al5.106Fe0 3773+Mg0.518) (T)(Si5.879Al0.121O18) (BO3)(3) [(OH)(2.656)O1.286F0.058], which represents disordered Na,Fe3+-rich feruvite (to "oxy-feruvite"). Contaminated pegmatite from Mirogov and its Ca-rich tourmalines are similar to other simple pegmatites from the Moldanubian Zone which have been contaminated by Ca,Fe-rich host rocks. The chemical compositions of Ca-rich schorl to Na-rich feruvite from various geological environments are similar, showing only minor dominance of Ca over Na.

Links

CZ.1.05/1.1.00/02.0068, interní kód MU
Name: CEITEC - středoevropský technologický institut (Acronym: CEITEC)
Investor: Ministry of Education, Youth and Sports of the CR, CEITEC - Central European Institute of Technology, 1.1 European Centres of Excellence
GAP210/10/0743, research and development project
Name: Chemické složení a stupeň strukturního uspořádání přírodních turmalínů - geochemické versus strukturní faktory
Investor: Czech Science Foundation, Chemical composition and structural order of natural tourmalines - geochemical versus crystal-structural constraints