MUKHERJEE, Titas, Sandipan SARKAR, Jaromír MAREK, Ennio ZANGRANDO and Pabitra CHATTOPADHYAY. Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study. Transition Metal Chemistry. Dordrecht: Kluwer Academic Publishers, 2012, vol. 37, No 2, p. 155-161. ISSN 0340-4285. Available from: https://dx.doi.org/10.1007/s11243-011-9569-9.
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Basic information
Original name Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
Authors MUKHERJEE, Titas (356 India), Sandipan SARKAR (356 India), Jaromír MAREK (203 Czech Republic, guarantor, belonging to the institution), Ennio ZANGRANDO (840 United States of America) and Pabitra CHATTOPADHYAY (356 India).
Edition Transition Metal Chemistry, Dordrecht, Kluwer Academic Publishers, 2012, 0340-4285.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher Netherlands
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 1.184
RIV identification code RIV/00216224:14740/12:00079730
Organization unit Central European Institute of Technology
Doi http://dx.doi.org/10.1007/s11243-011-9569-9
UT WoS 000302376000005
Keywords in English CALF THYMUS-DNA; PYRROLIDINE DITHIOCARBAMATE; FLUORESCENCE; SPECTROSCOPY; APOPTOSIS; CU2+
Tags kontrola MP, MP, rivok
Tags International impact, Reviewed
Changed by Changed by: Martina Prášilová, učo 342282. Changed: 24/3/2015 12:24.
Abstract
A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acid anion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.
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