Palladium(II) complexes of dithiocarbamic acids: synthesis,
characterization, crystal structure and DNA binding study

J 2012

Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study

MUKHERJEE, Titas, Sandipan SARKAR, Jaromír MAREK, Ennio ZANGRANDO, Pabitra CHATTOPADHYAY et. al.

Základní údaje

Originální název

Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study

Autoři

MUKHERJEE, Titas (356 Indie), Sandipan SARKAR (356 Indie), Jaromír MAREK (203 Česká republika, garant, domácí), Ennio ZANGRANDO (840 Spojené státy) a Pabitra CHATTOPADHYAY (356 Indie)

Vydání

Transition Metal Chemistry, Dordrecht, Kluwer Academic Publishers, 2012, 0340-4285

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.184

Kód RIV

RIV/00216224:14740/12:00079730

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1007/s11243-011-9569-9

UT WoS

000302376000005

Klíčová slova anglicky

CALF THYMUS-DNA; PYRROLIDINE DITHIOCARBAMATE; FLUORESCENCE; SPECTROSCOPY; APOPTOSIS; CU2+

Štítky

kontrola MP, MP, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 24. 3. 2015 12:24, Martina Prášilová

Anotace

V originále

A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acid anion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.

Citovat

MUKHERJEE, Titas, Sandipan SARKAR, Jaromír MAREK, Ennio ZANGRANDO a Pabitra CHATTOPADHYAY. Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study. Transition Metal Chemistry. Dordrecht: Kluwer Academic Publishers, 2012, roč. 37, č. 2, s. 155-161. ISSN 0340-4285. Dostupné z: https://dx.doi.org/10.1007/s11243-011-9569-9.

@article{1231653,
   author = {Mukherjee, Titas and Sarkar, Sandipan and Marek, Jaromír and Zangrando, Ennio and Chattopadhyay, Pabitra},
   article_location = {Dordrecht},
   article_number = {2},
   doi = {http://dx.doi.org/10.1007/s11243-011-9569-9},
   keywords = {CALF THYMUS-DNA; PYRROLIDINE DITHIOCARBAMATE; FLUORESCENCE; SPECTROSCOPY; APOPTOSIS; CU2+},
   language = {eng},
   issn = {0340-4285},
   journal = {Transition Metal Chemistry},
   title = {Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study},
   volume = {37},
   year = {2012}
}

TY  - JOUR
ID  - 1231653
AU  - Mukherjee, Titas - Sarkar, Sandipan - Marek, Jaromír - Zangrando, Ennio - Chattopadhyay, Pabitra
PY  - 2012
TI  - Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
JF  - Transition Metal Chemistry
VL  - 37
IS  - 2
SP  - 155-161
EP  - 155-161
PB  - Kluwer Academic Publishers
SN  - 03404285
KW  - CALF THYMUS-DNA
KW  - PYRROLIDINE DITHIOCARBAMATE
KW  - FLUORESCENCE
KW  - SPECTROSCOPY
KW  - APOPTOSIS
KW  - CU2+
N2  - A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acid anion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.
ER  -

MUKHERJEE, Titas, Sandipan SARKAR, Jaromír MAREK, Ennio ZANGRANDO a Pabitra CHATTOPADHYAY. Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study. \textit{Transition Metal Chemistry}. Dordrecht: Kluwer Academic Publishers, 2012, roč.~37, č.~2, s.~155-161. ISSN~0340-4285. Dostupné z: https://dx.doi.org/10.1007/s11243-011-9569-9.

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