Interaction of ferroceneboronic acid with diols at aqueous and
non-aqueous conditions - signalling and binding abilities of an
electrochemical probe for saccharides

J 2015

Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides

LACINA, Karel, Jan NOVOTNÝ, Zdeněk MORAVEC a Petr SKLÁDAL

Základní údaje

Originální název

Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides

Autoři

LACINA, Karel (203 Česká republika, garant, domácí), Jan NOVOTNÝ (203 Česká republika, domácí), Zdeněk MORAVEC (203 Česká republika, domácí) a Petr SKLÁDAL (203 Česká republika, domácí)

Vydání

Electrochimica Acta, Oxford, PERGAMON-ELSEVIER SCIENCE LTD, 2015, 0013-4686

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10405 Electrochemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.803

Kód RIV

RIV/00216224:14740/15:00082937

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1016/j.electacta.2014.12.009

UT WoS

000348450000036

Klíčová slova anglicky

Ferroceneboronic acid; Lewis acid; Non-aqueous environment; Binding properties; Detection of saccharides

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 29. 3. 2016 16:34, Mgr. Eva Špillingová

Anotace

V originále

Ferroceneboronic acid (FcBA) was employed as a model compound for clarification of binding and signalling properties of molecular probe for saccharides. As the simplest electrochemically active boronic acid, its interactions with diverse diols were studied in homogeneous phase under aqueous and non-aqueous conditions. The FcBA-diol system was examined by cyclic voltammetry resulting in two redox pairs corresponding to free and bound forms of FcBA. Redox potential of the bound form of FcBA was shifted in the cathodic direction in aqueous conditions due to coordination of the hydroxyl group to the boron atom. Oppositely, the anodic shift of the redox potential was observed upon the interaction of FcBA with diols in non-aqueous solvents. The binding properties and signalling mechanism of electrochemically active boronic acids were deduced and the assumptions resulting from the electrochemical behaviour were confirmed by 1H and 11B NMR spectroscopies. The binding constants of the tested diols in aqueous and non-aqueous media were determined and compared.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

EE2.3.30.0037, projekt VaV

Název: Zaměstnáním nejlepších mladých vědců k rozvoji mezinárodní spolupráce

Citovat

LACINA, Karel, Jan NOVOTNÝ, Zdeněk MORAVEC a Petr SKLÁDAL. Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides. Electrochimica Acta. Oxford: PERGAMON-ELSEVIER SCIENCE LTD, 2015, roč. 153, january, s. 280-286. ISSN 0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2014.12.009.

@article{1299850,
   author = {Lacina, Karel and Novotný, Jan and Moravec, Zdeněk and Skládal, Petr},
   article_location = {Oxford},
   article_number = {january},
   doi = {http://dx.doi.org/10.1016/j.electacta.2014.12.009},
   keywords = {Ferroceneboronic acid; Lewis acid; Non-aqueous environment; Binding properties; Detection of saccharides},
   language = {eng},
   issn = {0013-4686},
   journal = {Electrochimica Acta},
   title = {Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides},
   url = {http://www.sciencedirect.com/science/article/pii/S001346861402444X},
   volume = {153},
   year = {2015}
}

TY  - JOUR
ID  - 1299850
AU  - Lacina, Karel - Novotný, Jan - Moravec, Zdeněk - Skládal, Petr
PY  - 2015
TI  - Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides
JF  - Electrochimica Acta
VL  - 153
IS  - january
SP  - 280-286
EP  - 280-286
PB  - PERGAMON-ELSEVIER SCIENCE LTD
SN  - 00134686
KW  - Ferroceneboronic acid
KW  - Lewis acid
KW  - Non-aqueous environment
KW  - Binding properties
KW  - Detection of saccharides
UR  - http://www.sciencedirect.com/science/article/pii/S001346861402444X
L2  - http://www.sciencedirect.com/science/article/pii/S001346861402444X
N2  - Ferroceneboronic acid (FcBA) was employed as a model compound for clarification of binding and signalling properties of molecular probe for saccharides. As the simplest electrochemically active boronic acid, its interactions with diverse diols were studied in homogeneous phase under aqueous and non-aqueous conditions. The FcBA-diol system was examined by cyclic voltammetry resulting in two redox pairs corresponding to free and bound forms of FcBA. Redox potential of the bound form of FcBA was shifted in the cathodic direction in aqueous conditions due to coordination of the hydroxyl group to the boron atom. Oppositely, the anodic shift of the redox potential was observed upon the interaction of FcBA with diols in non-aqueous solvents. The binding properties and signalling mechanism of electrochemically active boronic acids were deduced and the assumptions resulting from the electrochemical behaviour were confirmed by 1H and 11B NMR spectroscopies. The binding constants of the tested diols in aqueous and non-aqueous media were determined and compared.
ER  -

LACINA, Karel, Jan NOVOTNÝ, Zdeněk MORAVEC a Petr SKLÁDAL. Interaction of ferroceneboronic acid with diols at aqueous and non-aqueous conditions - signalling and binding abilities of an electrochemical probe for saccharides. \textit{Electrochimica Acta}. Oxford: PERGAMON-ELSEVIER SCIENCE LTD, 2015, roč.~153, january, s.~280-286. ISSN~0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2014.12.009.

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