Syntheses and X-ray structures of heteroleptic octahedral Mn
(II)-xanthato complexes involving N-donor ligands

J 2015

Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands

JEREMIAS, Lukáš; Marek NEČAS; Zdeněk MORAVEC; Zdeněk TRÁVNÍČEK; Josef NOVOSAD et al.

Základní údaje

Originální název

Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands

Autoři

JEREMIAS, Lukáš; Marek NEČAS; Zdeněk MORAVEC; Zdeněk TRÁVNÍČEK a Josef NOVOSAD

Vydání

Journal of coordination chemistry, Malaysia, OPA, 2015, 0095-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.756

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/15:00084852

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Manganese(II) complexes; Crystal structures; Xanthates; Bipyridines; 1 10-Phenanthroline

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 3. 2018 10:20, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

A series of octahedral manganese(II) complexes involving xanthates and N-donor ligands, [Mn (S(2)COiBu)(2)(phen)] (1), [Mn(S(2)COiBu)(2)(2,2'-bpy)] (2), [Mn(S(2)COnPr)(2)(phen)] (3), [Mn(S(2)COnPr)(2) (2,2'-bpy)] (4), [Mn(S2COMe)(2)(2,2'-bpy)] (5), [Mn(S(2)COnPr)(2)(4,4'-bpy)](n), and [Mn-2(S(2)COnPr)(4) (4,4'-bpy)(3)] (6) (phen = 1,10-phenanthroline, bpy - bipyridine) was prepared. Complexes were characterized by elemental analysis, FTIR spectroscopy, TG/DSC analysis, and single-crystal X-ray diffraction. The structures are built of monomeric molecules of the complexes, except for 6 with the 4,4'-bipyridine ligand, which contains a binuclear complex and 1D polymeric zigzag chain in one crystal.

Přiložené soubory

JCoordChem_2015.pdf

Požádat o autorskou verzi souboru

Citovat

JEREMIAS, Lukáš; Marek NEČAS; Zdeněk MORAVEC; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands. Journal of coordination chemistry. Malaysia: OPA, 2015, roč. 68, č. 23, s. 4242-4254. ISSN 0095-8972. Dostupné z: https://doi.org/10.1080/00958972.2015.1102228.

@article{1318523,
   author = {Jeremias, Lukáš and Nečas, Marek and Moravec, Zdeněk and Trávníček, Zdeněk and Novosad, Josef},
   article_location = {Malaysia},
   article_number = {23},
   doi = {https://doi.org/10.1080/00958972.2015.1102228},
   keywords = {Manganese(II) complexes; Crystal structures; Xanthates; Bipyridines; 1 10-Phenanthroline},
   language = {eng},
   issn = {0095-8972},
   journal = {Journal of coordination chemistry},
   title = {Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands},
   volume = {68},
   year = {2015}
}

TY  - JOUR
ID  - 1318523
AU  - Jeremias, Lukáš - Nečas, Marek - Moravec, Zdeněk - Trávníček, Zdeněk - Novosad, Josef
PY  - 2015
TI  - Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands
JF  - Journal of coordination chemistry
VL  - 68
IS  - 23
SP  - 4242-4254
EP  - 4242-4254
PB  - OPA
SN  - 00958972
KW  - Manganese(II) complexes
KW  - Crystal structures
KW  - Xanthates
KW  - Bipyridines
KW  - 1 10-Phenanthroline
N2  - A series of octahedral manganese(II) complexes involving xanthates and N-donor ligands, [Mn (S(2)COiBu)(2)(phen)] (1), [Mn(S(2)COiBu)(2)(2,2'-bpy)] (2), [Mn(S(2)COnPr)(2)(phen)] (3), [Mn(S(2)COnPr)(2) (2,2'-bpy)] (4), [Mn(S2COMe)(2)(2,2'-bpy)] (5), [Mn(S(2)COnPr)(2)(4,4'-bpy)](n), and [Mn-2(S(2)COnPr)(4) (4,4'-bpy)(3)] (6) (phen = 1,10-phenanthroline, bpy - bipyridine) was prepared. Complexes were characterized by elemental analysis, FTIR spectroscopy, TG/DSC analysis, and single-crystal X-ray diffraction. The structures are built of monomeric molecules of the complexes, except for 6 with the 4,4'-bipyridine ligand, which contains a binuclear complex and 1D polymeric zigzag chain in one crystal.
ER  -

JEREMIAS, Lukáš; Marek NEČAS; Zdeněk MORAVEC; Zdeněk TRÁVNÍČEK a Josef NOVOSAD. Syntheses and X-ray structures of heteroleptic octahedral Mn (II)-xanthato complexes involving N-donor ligands. \textit{Journal of coordination chemistry}. Malaysia: OPA, 2015, roč.~68, č.~23, s.~4242-4254. ISSN~0095-8972. Dostupné z: https://doi.org/10.1080/00958972.2015.1102228.

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