Phenyl-methyl phosphazene derivatives for preparation and
modification of hydrophobic properties of polymeric nonwoven
textiles

J 2016

Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ et. al.

Základní údaje

Originální název

Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles

Autoři

BAČOVSKÁ, Radka (203 Česká republika, garant, domácí), Patty WISIAN-NEILSON (840 Spojené státy), Milan ALBERTI (203 Česká republika, domácí), Jiří PŘÍHODA (203 Česká republika, domácí), Lucie ZÁRYBNICKÁ (203 Česká republika) a Zbyněk VORÁČ (840 Spojené státy, domácí)

Vydání

Reactive and Functional Polymers, 2016, 1381-5148

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 3.151

Kód RIV

RIV/00216224:14310/16:00088827

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013

UT WoS

000371943600007

Klíčová slova anglicky

Polymeric nanofibers; Electrospinning technology; hydrophobicity; Ph-Me (t) additive; Ph-Me (p) polyphosphazene

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 14. 3. 2018 10:16, prof. RNDr. Jiří Příhoda, CSc.

Anotace

V originále

This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolayers that have significant hydrophobicity and thermal stability. The preparation of Ph-Me(p) is a multi-step reaction which produces a relatively low amount of the product. The second area of our interest was the creation of nanofibers formed from a mixture of some commercially available organic polymers and a cyclo-phosphazene derivative. In this case, tri(phenyl)-trimethyl-cyclo-triphosphazene, Ph-Me(t), whose synthesis is less complicated than its polymeric form, was used as an additive. The influence of the Ph-Me(t) additive in the nanofibers on the affinity to water was compared with the affinity of nanolayers made from a pure commercial polymer, i.e. without any phosphazene additive. It was also shown that the hydrophobic properties of fibers formed from Ph-Me(p) dissolved especially in THF are better than those of the nanofibers composed of a commercial polymer with the addition of Ph-Me(t).

Návaznosti

FR-TI1/413, projekt VaV

Název: *Nové technické polymery pro síťovatelné kompozity 2

Investor: Ministerstvo průmyslu a obchodu ČR, Nové technické polymery pro síťové kompozity 2

Citovat

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ a Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. Reactive and Functional Polymers. 2016, roč. 100, March, s. 53-63. ISSN 1381-5148. Dostupné z: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013.

@article{1332555,
   author = {Bačovská, Radka and WisianandNeilson, Patty and Alberti, Milan and Příhoda, Jiří and Zárybnická, Lucie and Voráč, Zbyněk},
   article_number = {March},
   doi = {http://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013},
   keywords = {Polymeric nanofibers; Electrospinning technology; hydrophobicity; Ph-Me (t) additive; Ph-Me (p) polyphosphazene},
   language = {eng},
   issn = {1381-5148},
   journal = {Reactive and Functional Polymers},
   title = {Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles},
   volume = {100},
   year = {2016}
}

TY  - JOUR
ID  - 1332555
AU  - Bačovská, Radka - Wisian-Neilson, Patty - Alberti, Milan - Příhoda, Jiří - Zárybnická, Lucie - Voráč, Zbyněk
PY  - 2016
TI  - Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles
JF  - Reactive and Functional Polymers
VL  - 100
IS  - March
SP  - 53-63
EP  - 53-63
SN  - 13815148
KW  - Polymeric nanofibers
KW  - Electrospinning technology
KW  - hydrophobicity
KW  - Ph-Me (t) additive
KW  - Ph-Me (p) polyphosphazene
N2  - This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolayers that have significant hydrophobicity and thermal stability. The preparation of Ph-Me(p) is a multi-step reaction which produces a relatively low amount of the product. The second area of our interest was the creation of nanofibers formed from a mixture of some commercially available organic polymers and a cyclo-phosphazene derivative. In this case, tri(phenyl)-trimethyl-cyclo-triphosphazene, Ph-Me(t), whose synthesis is less complicated than its polymeric form, was used as an additive. The influence of the Ph-Me(t) additive in the nanofibers on the affinity to water was compared with the affinity of nanolayers made from a pure commercial polymer, i.e. without any phosphazene additive. It was also shown that the hydrophobic properties of fibers formed from Ph-Me(p) dissolved especially in THF are better than those of the nanofibers composed of a commercial polymer with the addition of Ph-Me(t).
ER  -

BAČOVSKÁ, Radka, Patty WISIAN-NEILSON, Milan ALBERTI, Jiří PŘÍHODA, Lucie ZÁRYBNICKÁ a Zbyněk VORÁČ. Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles. \textit{Reactive and Functional Polymers}. 2016, roč.~100, March, s.~53-63. ISSN~1381-5148. Dostupné z: https://dx.doi.org/10.1016/j.reactfunctpolym.2015.12.013.

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