Dioxouranium complexes with pentadentate s-triazine Schiff base
ligands: Synthesis, crystal structure and optical properties

J 2016

Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ, Kamil WICHTERLE et. al.

Základní údaje

Originální název

Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties

Autoři

PAVELEK, Lubomír (203 Česká republika), Vít LADÁNYI (203 Česká republika, garant, domácí), Marek NEČAS (203 Česká republika, domácí), Silvie VALLOVÁ (203 Česká republika) a Kamil WICHTERLE (203 Česká republika)

Vydání

Polyhedron, Pergamon Press, 2016, 0277-5387

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Záznam v databázi WoS URL

Impakt faktor

Impact factor: 1.926

Kód RIV

RIV/00216224:14310/16:00089362

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.poly.2016.01.014

UT WoS

000374613700011

Klíčová slova česky

Uranyl(VI); komplexy; triazinové ligandy, rentgenová struktura, optické vlastnosti

Klíčová slova anglicky

Uranyl(VI); Complexes; Triazine ligands; X-ray structure; Optical properties

Štítky

AKR, CF SAXS, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 3. 2018 10:18, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

The article reports on the synthesis of three new organic ligands (s-triazine derivatives with salicylaldehyde and o-vanillin) and their complexes with uranyl(VI) salts. The uranyl(VI) complexes were characterized by single-crystal X-ray diffraction, UV–vis, fluorescence and IR spectroscopy. Thermal stabilities of the complexes were investigated using thermogravimetric analysis. The uranyl(VI) complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the uranyl(VI) ion in organic polydentate ligands.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

Citovat

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ a Kamil WICHTERLE. Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties. Polyhedron. Pergamon Press, 2016, roč. 107, March, s. 89-96. ISSN 0277-5387. Dostupné z: https://dx.doi.org/10.1016/j.poly.2016.01.014.

@article{1334864,
   author = {Pavelek, Lubomír and Ladányi, Vít and Nečas, Marek and Vallová, Silvie and Wichterle, Kamil},
   article_number = {March},
   doi = {http://dx.doi.org/10.1016/j.poly.2016.01.014},
   keywords = {Uranyl(VI); Complexes; Triazine ligands; X-ray structure; Optical properties},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties},
   url = {http://apps.webofknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=2&SID=N1ryueLHqgjaNJtWmkh&page=1&doc=1},
   volume = {107},
   year = {2016}
}

TY  - JOUR
ID  - 1334864
AU  - Pavelek, Lubomír - Ladányi, Vít - Nečas, Marek - Vallová, Silvie - Wichterle, Kamil
PY  - 2016
TI  - Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties
JF  - Polyhedron
VL  - 107
IS  - March
SP  - 89-96
EP  - 89-96
PB  - Pergamon Press
SN  - 02775387
KW  - Uranyl(VI)
KW  - Complexes
KW  - Triazine ligands
KW  - X-ray structure
KW  - Optical properties
UR  - http://apps.webofknowledge.com/full_record.do?product=UA&search_mode=GeneralSearch&qid=2&SID=N1ryueLHqgjaNJtWmkh&page=1&doc=1
L2  - http://www.sciencedirect.com/science/article/pii/S0277538716000188
N2  - The article reports on the synthesis of three new organic ligands (s-triazine derivatives with salicylaldehyde and o-vanillin) and their complexes with uranyl(VI) salts. The uranyl(VI) complexes were characterized by single-crystal X-ray diffraction, UV–vis, fluorescence and IR spectroscopy. Thermal stabilities of the complexes were investigated using thermogravimetric analysis. The uranyl(VI) complexes are insoluble in water and are soluble in DMF and DMSO. This study contributes to the understanding of the coordination behaviour of the uranyl(VI) ion in organic polydentate ligands.
ER  -

PAVELEK, Lubomír, Vít LADÁNYI, Marek NEČAS, Silvie VALLOVÁ a Kamil WICHTERLE. Dioxouranium complexes with pentadentate s-triazine Schiff base ligands: Synthesis, crystal structure and optical properties. \textit{Polyhedron}. Pergamon Press, 2016, roč.~107, March, s.~89-96. ISSN~0277-5387. Dostupné z: https://dx.doi.org/10.1016/j.poly.2016.01.014.

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