| LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES a Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. ChemElectroChem. Weinheim: WILEY-V C H VERLAG GMBH, 2015, roč. 2, č. 6, s. 867-871. ISSN 2196-0216. Dostupné z: https://dx.doi.org/10.1002/celc.201500016. |
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@article{1338621,
author = {Li, Meng and Xu, SuandYing and Gross, Andrew J. and Hammond, Jules L. and Estrela, Pedro and Weber, James and Lacina, Karel and James, Tony D. and Marken, Frank},
article_location = {Weinheim},
article_number = {6},
doi = {http://dx.doi.org/10.1002/celc.201500016},
keywords = {boronic acids; electroanalysis; ferrocene; saccharides; voltammetry},
language = {eng},
issn = {2196-0216},
journal = {ChemElectroChem},
title = {Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry},
url = {http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full},
volume = {2},
year = {2015}
}
TY - JOUR
ID - 1338621
AU - Li, Meng - Xu, Su-Ying - Gross, Andrew J. - Hammond, Jules L. - Estrela, Pedro - Weber, James - Lacina, Karel - James, Tony D. - Marken, Frank
PY - 2015
TI - Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry
JF - ChemElectroChem
VL - 2
IS - 6
SP - 867-871
EP - 867-871
PB - WILEY-V C H VERLAG GMBH
SN - 21960216
KW - boronic acids
KW - electroanalysis
KW - ferrocene
KW - saccharides
KW - voltammetry
UR - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
L2 - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
N2 - The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).
ER -
LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES a Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. \textit{ChemElectroChem}. Weinheim: WILEY-V C H VERLAG GMBH, 2015, roč.~2, č.~6, s.~867-871. ISSN~2196-0216. Dostupné z: https://dx.doi.org/10.1002/celc.201500016.
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