Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate
Generator–Collector Voltammetry and Square-Wave Voltammetry

J 2015

Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA et. al.

Základní údaje

Originální název

Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry

Autoři

LI, Meng (826 Velká Británie a Severní Irsko), Su-Ying XU (826 Velká Británie a Severní Irsko), Andrew J. GROSS (826 Velká Británie a Severní Irsko), Jules L. HAMMOND (826 Velká Británie a Severní Irsko), Pedro ESTRELA (826 Velká Británie a Severní Irsko), James WEBER (826 Velká Británie a Severní Irsko), Karel LACINA (203 Česká republika, garant, domácí), Tony D. JAMES (826 Velká Británie a Severní Irsko) a Frank MARKEN (826 Velká Británie a Severní Irsko)

Vydání

ChemElectroChem, Weinheim, WILEY-V C H VERLAG GMBH, 2015, 2196-0216

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10405 Electrochemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.506

Kód RIV

RIV/00216224:14740/15:00086932

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1002/celc.201500016

UT WoS

000357862100013

Klíčová slova anglicky

boronic acids; electroanalysis; ferrocene; saccharides; voltammetry

Štítky

rivok

Změněno: 5. 4. 2016 16:40, Mgr. Eva Špillingová

Anotace

V originále

The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

Citovat

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES a Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. ChemElectroChem. Weinheim: WILEY-V C H VERLAG GMBH, 2015, roč. 2, č. 6, s. 867-871. ISSN 2196-0216. Dostupné z: https://dx.doi.org/10.1002/celc.201500016.

@article{1338621,
   author = {Li, Meng and Xu, SuandYing and Gross, Andrew J. and Hammond, Jules L. and Estrela, Pedro and Weber, James and Lacina, Karel and James, Tony D. and Marken, Frank},
   article_location = {Weinheim},
   article_number = {6},
   doi = {http://dx.doi.org/10.1002/celc.201500016},
   keywords = {boronic acids; electroanalysis; ferrocene; saccharides; voltammetry},
   language = {eng},
   issn = {2196-0216},
   journal = {ChemElectroChem},
   title = {Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry},
   url = {http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full},
   volume = {2},
   year = {2015}
}

TY  - JOUR
ID  - 1338621
AU  - Li, Meng - Xu, Su-Ying - Gross, Andrew J. - Hammond, Jules L. - Estrela, Pedro - Weber, James - Lacina, Karel - James, Tony D. - Marken, Frank
PY  - 2015
TI  - Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry
JF  - ChemElectroChem
VL  - 2
IS  - 6
SP  - 867-871
EP  - 867-871
PB  - WILEY-V C H VERLAG GMBH
SN  - 21960216
KW  - boronic acids
KW  - electroanalysis
KW  - ferrocene
KW  - saccharides
KW  - voltammetry
UR  - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
L2  - http://onlinelibrary.wiley.com/doi/10.1002/celc.201500016/full
N2  - The interaction of ferrocene-boronic acid with fructose is investigated in aqueous 0.1 M phosphate buffer at pH 7, 8 and 9. Two voltammetric methods, based on 1) a dual-plate generator–collector micro-trench electrode (steady state) and 2) a square-wave voltammetry (transient) method, are applied and compared in terms of mechanistic resolution. A combination of experimental data is employed to obtain new insights into the binding rates and the cumulative binding constants for both the reduced ferrocene-boronic acid (pH dependent and weakly binding) and for the oxidised ferrocene-boronic acid (pH independent and strongly binding).
ER  -

LI, Meng, Su-Ying XU, Andrew J. GROSS, Jules L. HAMMOND, Pedro ESTRELA, James WEBER, Karel LACINA, Tony D. JAMES a Frank MARKEN. Ferrocene-Boronic Acid–Fructose Binding Based on Dual- Plate Generator–Collector Voltammetry and Square-Wave Voltammetry. \textit{ChemElectroChem}. Weinheim: WILEY-V C H VERLAG GMBH, 2015, roč.~2, č.~6, s.~867-871. ISSN~2196-0216. Dostupné z: https://dx.doi.org/10.1002/celc.201500016.

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