| ŠKODA, David, Aleš STÝSKALÍK, Zdeněk MORAVEC, Petr BEZDIČKA, Michal BABIAK, Mariana KLEMENTOVÁ, Craig E. BARNES and Jiří PINKAS. Novel non-hydrolytic templated sol-gel synthesis of mesoporous aluminosilicates and their use as aminolysis catalysts. RSC Advances. Cambridge: Royal Society of Chemistry, 2016, vol. 6, No 29, p. 24273-24284. ISSN 2046-2069. Available from: https://dx.doi.org/10.1039/c5ra24563j. |
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@article{1342895,
author = {Škoda, David and Stýskalík, Aleš and Moravec, Zdeněk and Bezdička, Petr and Babiak, Michal and Klementová, Mariana and Barnes, Craig E. and Pinkas, Jiří},
article_location = {Cambridge},
article_number = {29},
doi = {http://dx.doi.org/10.1039/c5ra24563j},
keywords = {Sol-gel; Non-hydrolytic condensation; Templating; Acetamide elimination; Mesoporous; Mixed oxides; Aluminosilicate; Aminolysis; Catalysis},
language = {eng},
issn = {2046-2069},
journal = {RSC Advances},
title = {Novel non-hydrolytic templated sol-gel synthesis of mesoporous aluminosilicates and their use as aminolysis catalysts},
url = {http://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C5RA24563J#!divAbstract},
volume = {6},
year = {2016}
}
TY - JOUR
ID - 1342895
AU - Škoda, David - Stýskalík, Aleš - Moravec, Zdeněk - Bezdička, Petr - Babiak, Michal - Klementová, Mariana - Barnes, Craig E. - Pinkas, Jiří
PY - 2016
TI - Novel non-hydrolytic templated sol-gel synthesis of mesoporous aluminosilicates and their use as aminolysis catalysts
JF - RSC Advances
VL - 6
IS - 29
SP - 24273-24284
EP - 24273-24284
PB - Royal Society of Chemistry
SN - 20462069
KW - Sol-gel
KW - Non-hydrolytic condensation
KW - Templating
KW - Acetamide elimination
KW - Mesoporous
KW - Mixed oxides
KW - Aluminosilicate
KW - Aminolysis
KW - Catalysis
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C5RA24563J#!divAbstract
L2 - http://pubs.rsc.org/en/Content/ArticleLanding/2016/RA/C5RA24563J#!divAbstract
N2 - A novel non-hydrolytic sol-gel (NHSG) synthesis of mesoporous aluminosilicate xerogels is presented. The polycondensation between silicon acetate, Si(OAc)(4), and tris(dimethylamido) alane, Al(NMe2)(3), leads to homogeneous aluminosilicate xerogels containing Si-O-Al linkages through dimethylacetamide elimination. The addition of Pluronic P123 and F127 templates provides stiff gels that are, after calcination at 500 degrees C, converted to stable mesoporous xerogels with a high surface area (>600 m(2) g(-1)) and wormhole-type pores (d = 5.9 nm). The xerogels exhibit high catalytic activity in aminolysis of styrene oxide (82% conversion) with the turnover frequency up to 100.
ER -
ŠKODA, David, Aleš STÝSKALÍK, Zdeněk MORAVEC, Petr BEZDIČKA, Michal BABIAK, Mariana KLEMENTOVÁ, Craig E. BARNES and Jiří PINKAS. Novel non-hydrolytic templated sol-gel synthesis of mesoporous aluminosilicates and their use as aminolysis catalysts. \textit{RSC Advances}. Cambridge: Royal Society of Chemistry, 2016, vol.~6, No~29, p.~24273-24284. ISSN~2046-2069. Available from: https://dx.doi.org/10.1039/c5ra24563j.
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