The internal heavy-atom effect on 3-phenylselanyl and
3-phenyltellanyl BODIPY derivatives studied by transient
absorption spectroscopy

J 2016

The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy

AL ANSHORI, Jamaludin, Tomáš SLANINA, Eduardo PALAO UTIEL a Petr KLÁN

Základní údaje

Originální název

The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy

Autoři

AL ANSHORI, Jamaludin (360 Indonésie, domácí), Tomáš SLANINA (203 Česká republika, domácí), Eduardo PALAO UTIEL (724 Španělsko, domácí) a Petr KLÁN (203 Česká republika, garant, domácí)

Vydání

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, CAMBRIDGE, ROYAL SOC CHEMISTRY, 2016, 1474-905X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10403 Physical chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.344

Kód RIV

RIV/00216224:14310/16:00089981

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1039/c5pp00366k

UT WoS

000370421800012

Klíčová slova anglicky

SINGLET OXYGEN GENERATION; TRIPLET EXCITED-STATE; FLUORESCENT-PROBE; LIVING CELLS; PHOTODYNAMIC THERAPY; UP-CONVERSION; DYES; PHOSPHORESCENCE; DESIGN; THIOLS

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 14. 4. 2017 14:50, Ing. Andrea Mikešková

Anotace

V originále

Three monosubstituted 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives were synthesized and their spectroscopic properties were characterized and compared to those of iodine and chlorine-atoms containing analogues as well as an unsubstituted BODIPY derivative. The fluorescence quantum yields were found to decrease, whereas the intersystem crossing quantum yields (Phi(ISC)), determined by transient spectroscopy, increased in the order of the H -> Cl -> Se/I -> Te substitution. The maximum Phi(ISC), found for the 3-phenyltellanyl derivative, was 59%. The results are interpreted in terms of the internal heavy-atom effect of the substituents.

Návaznosti

LM2011028, projekt VaV

Název: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX Národní infrastruktura pro výzkum toxických látek v prostředí

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

AL ANSHORI, Jamaludin, Tomáš SLANINA, Eduardo PALAO UTIEL a Petr KLÁN. The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES. CAMBRIDGE: ROYAL SOC CHEMISTRY, 2016, roč. 15, č. 2, s. 250-259. ISSN 1474-905X. Dostupné z: https://dx.doi.org/10.1039/c5pp00366k.

@article{1345762,
   author = {Al Anshori, Jamaludin and Slanina, Tomáš and Palao Utiel, Eduardo and Klán, Petr},
   article_location = {CAMBRIDGE},
   article_number = {2},
   doi = {http://dx.doi.org/10.1039/c5pp00366k},
   keywords = {SINGLET OXYGEN GENERATION; TRIPLET EXCITED-STATE; FLUORESCENT-PROBE; LIVING CELLS; PHOTODYNAMIC THERAPY; UP-CONVERSION; DYES; PHOSPHORESCENCE; DESIGN; THIOLS},
   language = {eng},
   issn = {1474-905X},
   journal = {PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES},
   title = {The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy},
   url = {http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract},
   volume = {15},
   year = {2016}
}

TY  - JOUR
ID  - 1345762
AU  - Al Anshori, Jamaludin - Slanina, Tomáš - Palao Utiel, Eduardo - Klán, Petr
PY  - 2016
TI  - The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy
JF  - PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
VL  - 15
IS  - 2
SP  - 250-259
EP  - 250-259
PB  - ROYAL SOC CHEMISTRY
SN  - 1474905X
KW  - SINGLET OXYGEN GENERATION
KW  - TRIPLET EXCITED-STATE
KW  - FLUORESCENT-PROBE
KW  - LIVING CELLS
KW  - PHOTODYNAMIC THERAPY
KW  - UP-CONVERSION
KW  - DYES
KW  - PHOSPHORESCENCE
KW  - DESIGN
KW  - THIOLS
UR  - http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract
L2  - http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract
N2  - Three monosubstituted 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives were synthesized and their spectroscopic properties were characterized and compared to those of iodine and chlorine-atoms containing analogues as well as an unsubstituted BODIPY derivative. The fluorescence quantum yields were found to decrease, whereas the intersystem crossing quantum yields (Phi(ISC)), determined by transient spectroscopy, increased in the order of the H -> Cl -> Se/I -> Te substitution. The maximum Phi(ISC), found for the 3-phenyltellanyl derivative, was 59%. The results are interpreted in terms of the internal heavy-atom effect of the substituents.
ER  -

AL ANSHORI, Jamaludin, Tomáš SLANINA, Eduardo PALAO UTIEL a Petr KLÁN. The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy. \textit{PHOTOCHEMICAL \&{} PHOTOBIOLOGICAL SCIENCES}. CAMBRIDGE: ROYAL SOC CHEMISTRY, 2016, roč.~15, č.~2, s.~250-259. ISSN~1474-905X. Dostupné z: https://dx.doi.org/10.1039/c5pp00366k.

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