Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with
(1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base
Ligand

a 2016

Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHHOLZ, Herman GORLS, Winfried PLASS et. al.

Základní údaje

Originální název

Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand

Autoři

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHHOLZ, Herman GORLS, Winfried PLASS a Jiří PINKAS

Vydání

42nd International Conference on Coordination Chemistry, 2016, Brest, France, 2016

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Francie

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Organizační jednotka

Středoevropský technologický institut

Klíčová slova česky

Koordinacni slouceniny; fosfonaty; fosfonova kyselina;

Klíčová slova anglicky

Coordination Compounds; (1-Amino-1-methyl-ethyl)phosphonic Acid; Schiff Base; Fe3+; Co2+; Ni2+; Dy3+; Gd3+

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 3. 2018 16:36, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

In the last decade, there has been a great interest in the phosphonic acid-based molecular complexes and coordination polymers. Because the M-O-P bonds are 1.5 times stronger then M-O-C bonds in carboxylates, phosphonates were used in the role of molecular precursors for the synthesis of new materials, such as polynuclear metal phosphonates, layered compounds, and porous metal-organic frameworks, with a wide range of properties and different applications. Phosphonate mononuclear complexes or molecular clusters with paramagnetic metal cations are very interesting objects because of their magnetic properties. We synthesized and isolated new molecular complexes and coordination polymers of AIPA ((1-amino-1-methyl-ethyl)phosphonic acid) and NaxSAA, x = 1, 2 (sodium hydrogen (2-{[(E)-(2-hydroxyphenyl)methylidene]amino}propan-2-yl)phosphonate, disodium hydrogen (2-{[(E)-(2-oxidophenyl)methylidene]amino}propan-2-yl)phosphonate) ligands with Fe3+, Ni2+, Co2+, Dy3+, and Gd3+. Their properties were studied by a variety of physicochemical methods including structural analyses by single-crystal X-ray diffraction methods. Their magnetic properties were studied on a SQUID magnetometer. Among the most interesting results obtained in this study are isolation and characterization of hexanuclear iron(III) phosphonate Fe6(NH3(CH3)2CPO3)12(OH)6].31H2O, a 1D coordination polymer of Fe with the SAA ligand, a series of heptanuclear Co2+ phosphonates with a Star-of-David structural motif, and a coordination polymer of Ni2+ with SAA ligands. Beside that, mononuclear isostructural complexes of Ni2+ and Co2+ with AIPA were obtained and characterized. The presence of non-coordinated amino groups in the complexes with AIPA makes these compounds potentional precursors for the synthesis of new extended structures.

Návaznosti

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHHOLZ, Herman GORLS, Winfried PLASS a Jiří PINKAS. Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand. In 42nd International Conference on Coordination Chemistry, 2016, Brest, France. 2016.

@proceedings{1350098,
   author = {Doroshenko, Iaroslav and Babiak, Michal and Buchholz, Axel and Gorls, Herman and Plass, Winfried and Pinkas, Jiří},
   booktitle = {42nd International Conference on Coordination Chemistry, 2016, Brest, France},
   keywords = {Coordination Compounds; (1-Amino-1-methyl-ethyl)phosphonic Acid; Schiff Base; Fe3+; Co2+; Ni2+; Dy3+; Gd3+},
   language = {eng},
   title = {Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand},
   url = {http://iccc2016.sciencesconf.org},
   year = {2016}
}

TY  - CONF
ID  - 1350098
AU  - Doroshenko, Iaroslav - Babiak, Michal - Buchholz, Axel - Gorls, Herman - Plass, Winfried - Pinkas, Jiří
PY  - 2016
TI  - Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand
KW  - Coordination Compounds
KW  - (1-Amino-1-methyl-ethyl)phosphonic Acid
KW  - Schiff Base
KW  - Fe3+
KW  - Co2+
KW  - Ni2+
KW  - Dy3+
KW  - Gd3+
UR  - http://iccc2016.sciencesconf.org
N2  - In the last decade, there has been a great interest in the phosphonic acid-based molecular complexes and coordination polymers. Because the M-O-P bonds are 1.5 times stronger then M-O-C bonds in carboxylates, phosphonates were used in the role of molecular precursors for the synthesis of new materials, such as polynuclear metal phosphonates, layered compounds, and porous metal-organic frameworks, with a wide range of properties and different applications. Phosphonate mononuclear complexes or molecular clusters with paramagnetic metal cations are very interesting objects because of their magnetic properties. We synthesized and isolated new molecular complexes and coordination polymers of AIPA ((1-amino-1-methyl-ethyl)phosphonic acid) and NaxSAA, x = 1, 2 (sodium hydrogen (2-{[(E)-(2-hydroxyphenyl)methylidene]amino}propan-2-yl)phosphonate, disodium hydrogen (2-{[(E)-(2-oxidophenyl)methylidene]amino}propan-2-yl)phosphonate) ligands with Fe3+, Ni2+, Co2+, Dy3+, and Gd3+. Their properties were studied by a variety of physicochemical methods including structural analyses by single-crystal X-ray diffraction methods. Their magnetic properties were studied on a SQUID magnetometer. Among the most interesting results obtained in this study are isolation and characterization of hexanuclear iron(III) phosphonate Fe6(NH3(CH3)2CPO3)12(OH)6].31H2O, a 1D coordination polymer of Fe with the SAA ligand, a series of heptanuclear Co2+ phosphonates with a Star-of-David structural motif, and a coordination polymer of Ni2+ with SAA ligands. Beside that, mononuclear isostructural complexes of Ni2+ and Co2+ with AIPA were obtained and characterized. The presence of non-coordinated amino groups in the complexes with AIPA makes these compounds potentional precursors for the synthesis of new extended structures.
ER  -

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHHOLZ, Herman GORLS, Winfried PLASS a Jiří PINKAS. Coordination Compounds of Fe3+, Co2+, Ni2+, Dy3+, and Gd3+ with (1-Amino-1-methyl-ethyl)phosphonic Acid and a New Schiff Base Ligand. In \textit{42nd International Conference on Coordination Chemistry, 2016, Brest, France}. 2016.

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