Analysis of brominated flame retardants and their derivatives
by atmospheric pressure chemical ionization using gas
chromatography coupled to tandem quadrupole mass spectrometry

J 2017

Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry

GENG, Dawei, Petr KUKUČKA a Ingrid Ericson JOGSTEN

Základní údaje

Originální název

Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry

Autoři

GENG, Dawei (156 Čína), Petr KUKUČKA (203 Česká republika, garant, domácí) a Ingrid Ericson JOGSTEN (752 Švédsko)

Vydání

Talanta, AMSTERDAM, Elsevier, 2017, 0039-9140

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.244

Kód RIV

RIV/00216224:14310/17:00096416

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.talanta.2016.10.060

UT WoS

000389088700083

Klíčová slova anglicky

BFR; PBDE; MeO-PBDE; gas chromatography-atmospheric pressure chemical ionization (GC-APCI); Tandem quadrupole mass spectrometry (MS/MS)

Štítky

NZ, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 3. 2018 14:47, Ing. Nicole Zrilić

Anotace

V originále

A validated method using an atmospheric pressure chemical ionization source for coupling gas chromatography (GC-APCI) to tandem quadrupole mass spectrometry (MS/MS) for the determination of brominated flame retardahts (BFRs) is presented. Polybrominated diphenyl ethers (PBDEs), their methoxylated derivatives (MeO-PBDEs) and other emerging BFRs were included in this study. The method showed good linearity and repeatability. The relative standard deviation (RSD) of the relative response factors (RRFs) of all compounds was below 16%. Repeatability for BFRs was tested on one or two concentration levels of calibration standards with RSDs for RRFs below 16%. The lowest calibration standards (0.075-0.1 pg/mu L for emerging BFRs, BDE 209 and MeO-PBDEs mixtures, 0.625-6.25 pg/mu L for Br1-9 PBDEs mixtures) were used as instrument detection limits (IDL). The method was applied on biotic samples, including fish, osprey, and seal. In general, BDE 209 and decabromodiphenyl ethane (DBDPE) were detected in 50% of the seal samples. A 100% detection rate was achieved for 6-MeO-BDE 47 in all the samples (72-580 pg/g ww in osprey samples, 24,00096,000 pg/g ww in seal samples and 78-99 pg/g ww in fish samples). All Br3-6 PBDEs (BDE 28, 47, 99, 100, 153, 154) were detected in all the samples (ranging from 12 to 20,000 pg/g ww), while BDE 183 was detected in 60% of the osprey eggs, 20% of the seal samples and below MDL in all fish samples. The results presented indicate the capability of the GC-APCI-MS/MS system for the detection and quantification of BFRs.

Návaznosti

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

GENG, Dawei, Petr KUKUČKA a Ingrid Ericson JOGSTEN. Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry. Talanta. AMSTERDAM: Elsevier, 2017, roč. 162, January, s. 618-624. ISSN 0039-9140. Dostupné z: https://dx.doi.org/10.1016/j.talanta.2016.10.060.

@article{1377512,
   author = {Geng, Dawei and Kukučka, Petr and Jogsten, Ingrid Ericson},
   article_location = {AMSTERDAM},
   article_number = {January},
   doi = {http://dx.doi.org/10.1016/j.talanta.2016.10.060},
   keywords = {BFR; PBDE; MeO-PBDE; gas chromatography-atmospheric pressure chemical ionization (GC-APCI); Tandem quadrupole mass spectrometry (MS/MS)},
   language = {eng},
   issn = {0039-9140},
   journal = {Talanta},
   title = {Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry},
   url = {http://dx.doi.org/10.1016/j.talanta.2016.10.060},
   volume = {162},
   year = {2017}
}

TY  - JOUR
ID  - 1377512
AU  - Geng, Dawei - Kukučka, Petr - Jogsten, Ingrid Ericson
PY  - 2017
TI  - Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry
JF  - Talanta
VL  - 162
IS  - January
SP  - 618-624
EP  - 618-624
PB  - Elsevier
SN  - 00399140
KW  - BFR
KW  - PBDE
KW  - MeO-PBDE
KW  - gas chromatography-atmospheric pressure chemical ionization (GC-APCI)
KW  - Tandem quadrupole mass spectrometry (MS/MS)
UR  - http://dx.doi.org/10.1016/j.talanta.2016.10.060
L2  - http://dx.doi.org/10.1016/j.talanta.2016.10.060
N2  - A validated method using an atmospheric pressure chemical ionization source for coupling gas chromatography (GC-APCI) to tandem quadrupole mass spectrometry (MS/MS) for the determination of brominated flame retardahts (BFRs) is presented. Polybrominated diphenyl ethers (PBDEs), their methoxylated derivatives (MeO-PBDEs) and other emerging BFRs were included in this study. The method showed good linearity and repeatability. The relative standard deviation (RSD) of the relative response factors (RRFs) of all compounds was below 16%. Repeatability for BFRs was tested on one or two concentration levels of calibration standards with RSDs for RRFs below 16%. The lowest calibration standards (0.075-0.1 pg/mu L for emerging BFRs, BDE 209 and MeO-PBDEs mixtures, 0.625-6.25 pg/mu L for Br1-9 PBDEs mixtures) were used as instrument detection limits (IDL). The method was applied on biotic samples, including fish, osprey, and seal. In general, BDE 209 and decabromodiphenyl ethane (DBDPE) were detected in 50% of the seal samples. A 100% detection rate was achieved for 6-MeO-BDE 47 in all the samples (72-580 pg/g ww in osprey samples, 24,00096,000 pg/g ww in seal samples and 78-99 pg/g ww in fish samples). All Br3-6 PBDEs (BDE 28, 47, 99, 100, 153, 154) were detected in all the samples (ranging from 12 to 20,000 pg/g ww), while BDE 183 was detected in 60% of the osprey eggs, 20% of the seal samples and below MDL in all fish samples. The results presented indicate the capability of the GC-APCI-MS/MS system for the detection and quantification of BFRs.
ER  -

GENG, Dawei, Petr KUKUČKA a Ingrid Ericson JOGSTEN. Analysis of brominated flame retardants and their derivatives by atmospheric pressure chemical ionization using gas chromatography coupled to tandem quadrupole mass spectrometry. \textit{Talanta}. AMSTERDAM: Elsevier, 2017, roč.~162, January, s.~618-624. ISSN~0039-9140. Dostupné z: https://dx.doi.org/10.1016/j.talanta.2016.10.060.

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