Solvent extraction of trivalent europium and americium into
nitrobenzene by using a synergistic mixture of hydrogen
dicarbollylcobaltate and bis(diphenylphosphino)acetylene
dioxide

J 2016

Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide

MAKRLIK, Emanuel, Petr VANURA a Zdeněk SPÍCHAL

Základní údaje

Originální název

Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide

Autoři

MAKRLIK, Emanuel (203 Česká republika), Petr VANURA (203 Česká republika) a Zdeněk SPÍCHAL (203 Česká republika, domácí)

Vydání

JOURNAL OF MOLECULAR LIQUIDS, AMSTERDAM, ELSEVIER SCIENCE BV, 2016, 0167-7322

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10403 Physical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Full Text

Impakt faktor

Impact factor: 3.648

Kód RIV

RIV/00216224:14310/16:00094255

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.molliq.2016.05.028

UT WoS

000383004100072

Klíčová slova anglicky

Europium and americium; Bis(diphenylphosphino)acetylene dioxide; Complexation; Extraction and stability constants; Water-nitrobenzene system

Štítky

AKR, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 17. 12. 2019 09:05, Mgr. Marie Šípková, DiS.

Anotace

V originále

Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of bis(diphenylphosphino)acetylene dioxide (DPPADO, L) was investigated. The equilibrium data were explained assuming that the species HL+, ML3+, ML23+, and ML33+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water were determined. It was found that the stability constants of the corresponding complexes EuLn3+ and AmLn3+, where n = 1,2,3 and L is DPPADO, in water-saturated nitrobenzene are comparable or the same, respectively.

Citovat

MAKRLIK, Emanuel, Petr VANURA a Zdeněk SPÍCHAL. Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide. JOURNAL OF MOLECULAR LIQUIDS. AMSTERDAM: ELSEVIER SCIENCE BV, 2016, roč. 221, SEP, s. 574-578. ISSN 0167-7322. Dostupné z: https://dx.doi.org/10.1016/j.molliq.2016.05.028.

@article{1380323,
   author = {Makrlik, Emanuel and Vanura, Petr and Spíchal, Zdeněk},
   article_location = {AMSTERDAM},
   article_number = {SEP},
   doi = {http://dx.doi.org/10.1016/j.molliq.2016.05.028},
   keywords = {Europium and americium; Bis(diphenylphosphino)acetylene dioxide; Complexation; Extraction and stability constants; Water-nitrobenzene system},
   language = {eng},
   issn = {0167-7322},
   journal = {JOURNAL OF MOLECULAR LIQUIDS},
   title = {Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide},
   url = {https://www.sciencedirect.com/science/article/pii/S0167732216303567},
   volume = {221},
   year = {2016}
}

TY  - JOUR
ID  - 1380323
AU  - Makrlik, Emanuel - Vanura, Petr - Spíchal, Zdeněk
PY  - 2016
TI  - Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide
JF  - JOURNAL OF MOLECULAR LIQUIDS
VL  - 221
IS  - SEP
SP  - 574-578
EP  - 574-578
PB  - ELSEVIER SCIENCE BV
SN  - 01677322
KW  - Europium and americium
KW  - Bis(diphenylphosphino)acetylene dioxide
KW  - Complexation
KW  - Extraction and stability constants
KW  - Water-nitrobenzene system
UR  - https://www.sciencedirect.com/science/article/pii/S0167732216303567
L2  - https://www.sciencedirect.com/science/article/pii/S0167732216303567
N2  - Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of bis(diphenylphosphino)acetylene dioxide (DPPADO, L) was investigated. The equilibrium data were explained assuming that the species HL+, ML3+, ML23+, and ML33+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water were determined. It was found that the stability constants of the corresponding complexes EuLn3+ and AmLn3+, where n = 1,2,3 and L is DPPADO, in water-saturated nitrobenzene are comparable or the same, respectively.
ER  -

MAKRLIK, Emanuel, Petr VANURA a Zdeněk SPÍCHAL. Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide. \textit{JOURNAL OF MOLECULAR LIQUIDS}. AMSTERDAM: ELSEVIER SCIENCE BV, 2016, roč.~221, SEP, s.~574-578. ISSN~0167-7322. Dostupné z: https://dx.doi.org/10.1016/j.molliq.2016.05.028.

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