Selective electrocatalysis of reduced graphene oxide towards
hydrogen peroxide aiming oxidases-based biosensing: Caution
while interpreting

J 2017

Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting

LACINA, Karel, Ondřej KUBESA, Petr VANÝSEK, Veronika HORÁČKOVÁ, Zdeněk MORAVEC et. al.

Základní údaje

Originální název

Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting

Autoři

LACINA, Karel (203 Česká republika, garant, domácí), Ondřej KUBESA (203 Česká republika, domácí), Petr VANÝSEK (203 Česká republika), Veronika HORÁČKOVÁ (203 Česká republika, domácí), Zdeněk MORAVEC (203 Česká republika, domácí) a Petr SKLÁDAL (203 Česká republika, domácí)

Vydání

Electrochimica Acta, Oxford, Pergamon-Elsevier, 2017, 0013-4686

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10600 1.6 Biological sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.116

Kód RIV

RIV/00216224:14740/17:00096692

Organizační jednotka

Středoevropský technologický institut

DOI

http://dx.doi.org/10.1016/j.electacta.2016.11.172

UT WoS

000392773100001

Klíčová slova anglicky

Reduced graphene oxide; electrocatalysis; hydrogen peroxide; enzymatic (bio)sensors; ascorbic acid

Štítky

CF NANO, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 31. 5. 2017 15:15, Mgr. Eva Špillingová

Anotace

V originále

Graphene is currently often reported as a superior electrochemical (and not only) material. Here we assess critically the often-reported electrocatalytic behaviour of an electrode modified with reduced graphene oxide (rGO) towards H2O2. Two different electrode materials - gold and glassy carbon - were modified with rGO and comparative measurements in the presence of H2O2 and two ordinary electrochemical interferents - ascorbic acid and dopamine - were performed. Neither selectivity nor significant electrocatalytic abilities of rGO modified electrodes were observed. Only the mass transfer was enhanced due to the improvement of the parameters applicable for general electrochemistry on nanoparticles - diffusion layer and electroactive area. (C) 2016 Elsevier Ltd. All rights reserved.

Návaznosti

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

LACINA, Karel, Ondřej KUBESA, Petr VANÝSEK, Veronika HORÁČKOVÁ, Zdeněk MORAVEC a Petr SKLÁDAL. Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting. Electrochimica Acta. Oxford: Pergamon-Elsevier, 2017, roč. 223, January, s. 1-7. ISSN 0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2016.11.172.

@article{1380719,
   author = {Lacina, Karel and Kubesa, Ondřej and Vanýsek, Petr and Horáčková, Veronika and Moravec, Zdeněk and Skládal, Petr},
   article_location = {Oxford},
   article_number = {January},
   doi = {http://dx.doi.org/10.1016/j.electacta.2016.11.172},
   keywords = {Reduced graphene oxide; electrocatalysis; hydrogen peroxide; enzymatic (bio)sensors; ascorbic acid},
   language = {eng},
   issn = {0013-4686},
   journal = {Electrochimica Acta},
   title = {Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting},
   url = {http://www.sciencedirect.com/science/article/pii/S0013468616325270},
   volume = {223},
   year = {2017}
}

TY  - JOUR
ID  - 1380719
AU  - Lacina, Karel - Kubesa, Ondřej - Vanýsek, Petr - Horáčková, Veronika - Moravec, Zdeněk - Skládal, Petr
PY  - 2017
TI  - Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting
JF  - Electrochimica Acta
VL  - 223
IS  - January
SP  - 1-7
EP  - 1-7
PB  - Pergamon-Elsevier
SN  - 00134686
KW  - Reduced graphene oxide
KW  - electrocatalysis
KW  - hydrogen peroxide
KW  - enzymatic (bio)sensors
KW  - ascorbic acid
UR  - http://www.sciencedirect.com/science/article/pii/S0013468616325270
L2  - http://www.sciencedirect.com/science/article/pii/S0013468616325270
N2  - Graphene is currently often reported as a superior electrochemical (and not only) material. Here we assess critically the often-reported electrocatalytic behaviour of an electrode modified with reduced graphene oxide (rGO) towards H2O2. Two different electrode materials - gold and glassy carbon - were modified with rGO and comparative measurements in the presence of H2O2 and two ordinary electrochemical interferents - ascorbic acid and dopamine - were performed. Neither selectivity nor significant electrocatalytic abilities of rGO modified electrodes were observed. Only the mass transfer was enhanced due to the improvement of the parameters applicable for general electrochemistry on nanoparticles - diffusion layer and electroactive area. (C) 2016 Elsevier Ltd. All rights reserved.
ER  -

LACINA, Karel, Ondřej KUBESA, Petr VANÝSEK, Veronika HORÁČKOVÁ, Zdeněk MORAVEC a Petr SKLÁDAL. Selective electrocatalysis of reduced graphene oxide towards hydrogen peroxide aiming oxidases-based biosensing: Caution while interpreting. \textit{Electrochimica Acta}. Oxford: Pergamon-Elsevier, 2017, roč.~223, January, s.~1-7. ISSN~0013-4686. Dostupné z: https://dx.doi.org/10.1016/j.electacta.2016.11.172.

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