FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY

D 2017

FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY

TRNKOVÁ, Libuše

Základní údaje

Originální název

FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY

Autoři

TRNKOVÁ, Libuše (203 Česká republika, garant, domácí)

Vydání

1. vyd. Brno, XVII. Workshop of Physical Chemists and Electrochemists, od s. 23-24, 2 s. 2017

Nakladatel

Masarykova univerzita

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10403 Physical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Forma vydání

elektronická verze "online"

Kód RIV

RIV/00216224:14310/17:00096905

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-80-210-8580-0

Klíčová slova anglicky

elimination polarography; elimination voltammetry; adsorbed electroactive species; oligodeoxynucleotides

Štítky

NZ, rivok

Změněno: 21. 3. 2018 22:18, Ing. Nicole Zrilić

Anotace

V originále

Thirty years ago the theory of elimination polarography (EP) and elimination voltammetry with linear scan (EVLS) was firstly published and experimentally verified [1-6]. The elimination procedure applied in both polarography as well as voltammetry can be considered as a mathematical model of the transformation of current-potential curves capable of eliminating some selected current components, while conserving others by means of elimination functions. While the elimination functions in EP use the differential dependence of a current component on time, the EVLS works on the basis of the different dependence of current components (diffusion, charging and kinetic) on the scan rate. Thereafter, the chosen EVLS function needs two or three voltammetric (LSV or CV) curves measured at different scan rates only. Due to longer time and experimental demands of elimination polarography, EVLS has been achieving greater development and usage during last decade. To this date it has found applications not only in electroanalysis, but also in studying electrode processes of inorganic and organic electroactive substances at mercury, silver and/or graphite electrodes [7-35]. For fully adsorbed electroactive species the function eliminating charging and kinetic current components, and conserving the diffusion current component, yields the specific, sensitive and well developed peak-counterpeak (p-cp) signal [7,8,16]. This signal, usually 10-20 times higher than corresponding measured voltammetric peak, is successfully employed in the analysis of nucleic acids and short homo- or hetero-deoxyoligonucleotides (ODNs) containing adenine and cytosine [10,15,17,19,21,22,33,34]. Moreover, it has been shown that the EVLS in combination with adsorptive stripping procedure is a promising tool for achieving very good resolution of electrode processes, for qualitative and quantitative analysis of ODNs and their components, as well as for the identification of ODN structures [10,15,17,19,21,22,33,34].

Návaznosti

LD15058, projekt VaV

Název: Příprava substrátů pro povrchově zesílenou Ramanovu spektroskopii pomocí elektrochemických, elektroforetických a jiskrový výboj využívajících technik. (Akronym: ELE-SERS)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Příprava substrátů pro povrchově zesílenou Ramanovu spektroskopii pomocí elektrochemických, elektroforetických a jiskrový výboj využívajících technik.

Citovat

TRNKOVÁ, Libuše. FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY. Online. In Libuše Trnková. XVII. Workshop of Physical Chemists and Electrochemists. 1. vyd. Brno: Masarykova univerzita, 2017, s. 23-24. ISBN 978-80-210-8580-0.

@inproceedings{1382513,
   author = {Trnková, Libuše},
   address = {Brno},
   booktitle = {XVII. Workshop of Physical Chemists and Electrochemists},
   edition = {1},
   editor = {Libuše Trnková},
   keywords = {elimination polarography; elimination voltammetry; adsorbed electroactive species; oligodeoxynucleotides},
   howpublished = {elektronická verze "online"},
   language = {eng},
   location = {Brno},
   isbn = {978-80-210-8580-0},
   pages = {23-24},
   publisher = {Masarykova univerzita},
   title = {FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY},
   year = {2017}
}

TY  - JOUR
ID  - 1382513
AU  - Trnková, Libuše
PY  - 2017
TI  - FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY
PB  - Masarykova univerzita
CY  - Brno
SN  - 9788021085800
KW  - elimination polarography
KW  - elimination voltammetry
KW  - adsorbed electroactive species
KW  - oligodeoxynucleotides
N2  - Thirty years ago the theory of elimination polarography (EP) and elimination voltammetry with linear scan (EVLS) was firstly published and experimentally verified [1-6]. The elimination procedure applied in both polarography as well as voltammetry can be considered as a mathematical model of the transformation of current-potential curves capable of eliminating some selected current components, while conserving others by means of elimination functions. While the elimination functions in EP use the differential dependence of a current component on time, the EVLS works on the basis of the different dependence of current components (diffusion, charging and kinetic) on the scan rate. Thereafter, the chosen EVLS function needs two or three voltammetric (LSV or CV) curves measured at different scan rates only. Due to longer time and experimental demands of elimination polarography, EVLS has been achieving greater development and usage during last decade. To this date it has found applications not only in electroanalysis, but also in studying electrode processes of inorganic and organic electroactive substances at mercury, silver and/or graphite electrodes [7-35]. For fully adsorbed electroactive species the function eliminating charging and kinetic current components, and conserving the diffusion current component, yields the specific, sensitive and well developed peak-counterpeak (p-cp) signal [7,8,16]. This signal, usually 10-20 times higher than corresponding measured voltammetric peak, is successfully employed in the analysis of nucleic acids and short homo- or hetero-deoxyoligonucleotides (ODNs) containing adenine and cytosine [10,15,17,19,21,22,33,34]. Moreover, it has been shown that the EVLS in combination with adsorptive stripping procedure is a promising tool for achieving very good resolution of electrode processes, for qualitative and quantitative analysis of ODNs and their components, as well as for the identification of ODN structures [10,15,17,19,21,22,33,34].
ER  -

TRNKOVÁ, Libuše. FROM POLAROGRAPHY TO ELIMINATION VOLTAMMETRY. Online. In Libuše Trnková. \textit{XVII. Workshop of Physical Chemists and Electrochemists}. 1. vyd. Brno: Masarykova univerzita, 2017, s.~23-24. ISBN~978-80-210-8580-0.

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