Application of a macrocyclic compound, bambus[6]uril, in
tailor-made liquid membranes for highly selective
electromembrane extractions of inorganic anions

J 2017

Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions

SLAMPOVA, Andrea, Vladimír ŠINDELÁŘ a Pavel KUBÁŇ

Základní údaje

Originální název

Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions

Autoři

SLAMPOVA, Andrea (203 Česká republika), Vladimír ŠINDELÁŘ (203 Česká republika, garant, domácí) a Pavel KUBÁŇ (203 Česká republika)

Vydání

Analytica Chimica Acta, Amsterdam, Elsevier Science publishers, 2017, 0003-2670

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.123

Kód RIV

RIV/00216224:14310/17:00098936

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.aca.2016.11.010

UT WoS

000390629500005

Klíčová slova anglicky

Extraction selectivity; Electromembrane extractions; Host-guest interactions; Inorganic anions; Liquid membranes; Macrocyclic compounds

Štítky

NZ, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 28. 3. 2018 15:57, Ing. Nicole Zrilić

Anotace

V originále

A tailor-made liquid membrane consisting of a resistive organic solvent (nitrobenzene, NB) and a highly selective non-ionic macrocyclic compound (bambus[6]uril, BU6) was employed for electromembrane extraction (EME) of inorganic anions. BU6 facilitates strong host-guest interactions of its internal cavity with selected inorganic anions only and its presence in the liquid membrane ensured excellent selectivity of the EME process. EME transfers were directly related to association constants between BU6 and inorganic anions and nearly absolute selectivity was achieved for EMEs of iodide, bromide and perchlorate. Major inorganic anions (chloride, nitrate, sulphate and carbonate), which exhibit low interactions with BU6 cavity, were efficiently eliminated from the EME transfer. No interferences were observed for EMEs of target analytes from samples containing up to 100.000-fold higher concentrations of the major anions. Addition of species-specific macrocyclic modifiers to free and supported liquid membranes might thus open new directions in fine-tuning of EME selectivity. At optimized EME conditions (polypropylene hollow fiber impregnated with NB + 3% (w/w) BU6, extraction voltage 25 V, extraction time 15 min, deionized water as acceptor solution) perchlorate was selectively extracted from tap water at concentrations below the guideline value recommended by United States Environmental Protection Agency. Excellent selectivity of the tailor-made liquid membrane was further demonstrated by EME of bromide from sea water.

Citovat

SLAMPOVA, Andrea, Vladimír ŠINDELÁŘ a Pavel KUBÁŇ. Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions. Analytica Chimica Acta. Amsterdam: Elsevier Science publishers, 2017, roč. 950, JANUARY, s. 49-56. ISSN 0003-2670. Dostupné z: https://dx.doi.org/10.1016/j.aca.2016.11.010.

@article{1400316,
   author = {Slampova, Andrea and Šindelář, Vladimír and Kubáň, Pavel},
   article_location = {Amsterdam},
   article_number = {JANUARY},
   doi = {http://dx.doi.org/10.1016/j.aca.2016.11.010},
   keywords = {Extraction selectivity; Electromembrane extractions; Host-guest interactions; Inorganic anions; Liquid membranes; Macrocyclic compounds},
   language = {eng},
   issn = {0003-2670},
   journal = {Analytica Chimica Acta},
   title = {Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions},
   url = {http://www.sciencedirect.com/science/article/pii/S0003267016312958?via%3Dihub},
   volume = {950},
   year = {2017}
}

TY  - JOUR
ID  - 1400316
AU  - Slampova, Andrea - Šindelář, Vladimír - Kubáň, Pavel
PY  - 2017
TI  - Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions
JF  - Analytica Chimica Acta
VL  - 950
IS  - JANUARY
SP  - 49-56
EP  - 49-56
PB  - Elsevier Science publishers
SN  - 00032670
KW  - Extraction selectivity
KW  - Electromembrane extractions
KW  - Host-guest interactions
KW  - Inorganic anions
KW  - Liquid membranes
KW  - Macrocyclic compounds
UR  - http://www.sciencedirect.com/science/article/pii/S0003267016312958?via%3Dihub
L2  - http://www.sciencedirect.com/science/article/pii/S0003267016312958?via%3Dihub
N2  - A tailor-made liquid membrane consisting of a resistive organic solvent (nitrobenzene, NB) and a highly selective non-ionic macrocyclic compound (bambus[6]uril, BU6) was employed for electromembrane extraction (EME) of inorganic anions. BU6 facilitates strong host-guest interactions of its internal cavity with selected inorganic anions only and its presence in the liquid membrane ensured excellent selectivity of the EME process. EME transfers were directly related to association constants between BU6 and inorganic anions and nearly absolute selectivity was achieved for EMEs of iodide, bromide and perchlorate. Major inorganic anions (chloride, nitrate, sulphate and carbonate), which exhibit low interactions with BU6 cavity, were efficiently eliminated from the EME transfer. No interferences were observed for EMEs of target analytes from samples containing up to 100.000-fold higher concentrations of the major anions. Addition of species-specific macrocyclic modifiers to free and supported liquid membranes might thus open new directions in fine-tuning of EME selectivity. At optimized EME conditions (polypropylene hollow fiber impregnated with NB + 3% (w/w) BU6, extraction voltage 25 V, extraction time 15 min, deionized water as acceptor solution) perchlorate was selectively extracted from tap water at concentrations below the guideline value recommended by United States Environmental Protection Agency. Excellent selectivity of the tailor-made liquid membrane was further demonstrated by EME of bromide from sea water.
ER  -

SLAMPOVA, Andrea, Vladimír ŠINDELÁŘ a Pavel KUBÁŇ. Application of a macrocyclic compound, bambus[6]uril, in tailor-made liquid membranes for highly selective electromembrane extractions of inorganic anions. \textit{Analytica Chimica Acta}. Amsterdam: Elsevier Science publishers, 2017, roč.~950, JANUARY, s.~49-56. ISSN~0003-2670. Dostupné z: https://dx.doi.org/10.1016/j.aca.2016.11.010.

Podrobný výpis o publikaci