COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL
(II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW
SCHIFF BASE LIGAND

a 2017

COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHOLZ, Winfried PLASS, Jiří PINKAS et. al.

Základní údaje

Originální název

COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND

Autoři

DOROSHENKO, Iaroslav (804 Ukrajina, domácí), Michal BABIAK (703 Slovensko, domácí), Axel BUCHOLZ (276 Německo), Winfried PLASS (276 Německo) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

17th Intl. Seminar of PhD Students on Organomet.Coord. Chemistry, Kraskov, CR, 2017

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/17:00099174

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

phosphonic acid; molecular complexes; Fe; Ni; Co

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 3. 2018 15:14, prof. RNDr. Jiří Pinkas, Ph.D.

Anotace

V originále

In the last decade, there has been a great interest in the phosphonic acid-based molecular complexes and coordination polymers. Because the M-O-P bonds are stronger then the M-O-C bonds in carboxylates, phosphonates are widely used in the synthesis of different metal-organic materials, such as polynuclear metal phosphonates, layered compounds, and porous metal-organic frameworks,1 with a broad range of properties and different applications.2,3 Molecular phosphonates are very interesting objects, because such complexes can be applied as molecular precursors to MOF’s due to their stability. Mononuclear complexes or molecular clusters with paramagnetic metal cations are also very interesting compounds because of their magnetic properties. We synthesized and isolated new molecular complexes and coordination polymers of H2AIPA ((1-amino-1-methyl-ethyl)phosphonic acid) and Na2SAA (disodium (2-{[(E)-(2-oxidophenyl)methylidene]ammonio}propan-2-yl)phosphonate) ligands with Fe3+, Ni2+, and Co2+. Their properties were studied by a variety of physicochemical methods including structural analysis by the single-crystal X-ray diffraction method. Their magnetic properties were studied on a SQUID magnetometer. The most interesting results obtained in this study are the isolation and characterization of hexanuclear iron(III) phosphonate [Fe6(HAIPA)12(OH)6].nH2O, a 1D coordination polymer of Fe with the H2SAA ligand, a series of heptanuclear Co2+ phosphonates with a Star-of-David structural motif and related coordination polymers. A coordination polymer of Ni2+ with the H2SAA ligand was also isolated. Besides that, mononuclear isostructural complexes of Ni2+ and Co2+ with H2AIPA were obtained and characterized. The presence of non-coordinated amino groups in the complexes with H2AIPA and –OH groups in Co2+ complexes with Na2SAA makes these compounds potential precursors for the synthesis of new extended structures. Attempts of modification of [Co7(SAA)2(XSAA)4].nMeOH, X = H, Na, by SiCl4 were carried out.

Návaznosti

LM2015043, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHOLZ, Winfried PLASS a Jiří PINKAS. COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND. In 17th Intl. Seminar of PhD Students on Organomet.Coord. Chemistry, Kraskov, CR. 2017.

@proceedings{1402076,
   author = {Doroshenko, Iaroslav and Babiak, Michal and Bucholz, Axel and Plass, Winfried and Pinkas, Jiří},
   booktitle = {17th Intl. Seminar of PhD Students on Organomet.Coord. Chemistry, Kraskov, CR},
   keywords = {phosphonic acid; molecular complexes; Fe; Ni; Co},
   language = {eng},
   title = {COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND},
   year = {2017}
}

TY  - CONF
ID  - 1402076
AU  - Doroshenko, Iaroslav - Babiak, Michal - Bucholz, Axel - Plass, Winfried - Pinkas, Jiří
PY  - 2017
TI  - COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND
KW  - phosphonic acid
KW  - molecular complexes
KW  - Fe
KW  - Ni
KW  - Co
N2  - In the last decade, there has been a great interest in the phosphonic acid-based molecular complexes and coordination polymers. Because the M-O-P bonds are stronger then the M-O-C bonds in carboxylates, phosphonates are widely used in the synthesis of different metal-organic materials, such as polynuclear metal phosphonates, layered compounds, and porous metal-organic frameworks,1 with a broad range of properties and different applications.2,3 Molecular phosphonates are very interesting objects, because such complexes can be applied as molecular precursors to MOF’s due to their stability. Mononuclear complexes or molecular clusters with paramagnetic metal cations are also very interesting compounds because of their magnetic properties. We synthesized and isolated new molecular complexes and coordination polymers of H2AIPA ((1-amino-1-methyl-ethyl)phosphonic acid) and Na2SAA (disodium (2-{[(E)-(2-oxidophenyl)methylidene]ammonio}propan-2-yl)phosphonate) ligands with Fe3+, Ni2+, and Co2+. Their properties were studied by a variety of physicochemical methods including structural analysis by the single-crystal X-ray diffraction method. Their magnetic properties were studied on a SQUID magnetometer. The most interesting results obtained in this study are the isolation and characterization of hexanuclear iron(III) phosphonate [Fe6(HAIPA)12(OH)6].nH2O, a 1D coordination polymer of Fe with the H2SAA ligand, a series of heptanuclear Co2+ phosphonates with a Star-of-David structural motif and related coordination polymers. A coordination polymer of Ni2+ with the H2SAA ligand was also isolated. Besides that, mononuclear isostructural complexes of Ni2+ and Co2+ with H2AIPA were obtained and characterized. The presence of non-coordinated amino groups in the complexes with H2AIPA and –OH groups in Co2+ complexes with Na2SAA makes these compounds potential precursors for the synthesis of new extended structures. Attempts of modification of [Co7(SAA)2(XSAA)4].nMeOH, X = H, Na, by SiCl4 were carried out.
ER  -

DOROSHENKO, Iaroslav, Michal BABIAK, Axel BUCHOLZ, Winfried PLASS a Jiří PINKAS. COORDINATION COMPOUNDS OF IRON (III), COBALT (II), AND NICKEL (II) WITH (1-AMINO-1-METHYL-ETHYL)PHOSPHONIC ACID AND A NEW SCHIFF BASE LIGAND. In \textit{17th Intl. Seminar of PhD Students on Organomet.Coord. Chemistry, Kraskov, CR}. 2017.

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