Polybrominated diphenyl ethers (PBDEs) in background air around
the Aegean: implications for phase partitioning and size
distribution

J 2017

Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution

BESIS, Athanasios, Gerhard LAMMEL, Petr KUKUČKA, Constantini SAMARA, Aysun SOFUOGLU et. al.

Základní údaje

Originální název

Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution

Autoři

BESIS, Athanasios (300 Řecko), Gerhard LAMMEL (276 Německo, garant, domácí), Petr KUKUČKA (203 Česká republika, domácí), Constantini SAMARA (300 Řecko), Aysun SOFUOGLU (792 Turecko), Yetkin DUMANOGLU (792 Turecko), Kostas ELEFTHERIADIS (300 Řecko), Giorgos KOUVARAKIS (300 Řecko), Sait C. SOFUOGLU (792 Turecko), Vassiliki VASSILATOU (300 Řecko) a Dimitra VOUTSA (300 Řecko)

Vydání

Environmental Science and Pollution Research, HEIDELBERG, SPRINGER HEIDELBERG, 2017, 0944-1344

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.800

Kód RIV

RIV/00216224:14310/17:00095521

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1007/s11356-017-0285-7

UT WoS

000417874400046

Klíčová slova anglicky

Absorption/adsorption models; Gas/particle partitioning; Long-range transport; Aerosol mass size distribution

Štítky

NZ, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 10. 4. 2018 17:42, Ing. Nicole Zrilić

Anotace

V originále

The occurrence and atmospheric behavior of tri- to deca-polybrominated diphenyl ethers (PBDEs) were investigated during a 2-week campaign concurrently conducted in July 2012 at four background sites around the Aegean Sea. The study focused on the gas/particle (G/P) partitioning at three sites (Ag. Paraskevi/central Greece/suburban, Finokalia/southern Greece/remote coastal, and Urla/Turkey/rural coastal) and on the size distribution at two sites (Neochorouda/northern Greece/rural inland and Finokalia/southern Greece/remote coastal). The lowest mean total (G + P) concentrations of a(7)PBDE (BDE-28, BDE-47, BDE-66, BDE-99, BDE-100, BDE-153, BDE-154) and BDE-209 (0.81 and 0.95 pg m(-3), respectively) were found at the remote site Finokalia. Partitioning coefficients, K (P), were calculated, and their linear relationships with ambient temperature and the physicochemical properties of the analyzed PBDE congeners, i.e., the subcooled liquid pressure (P (L)A degrees) and the octanol-air partition coefficient (K (OA)), were investigated. The equilibrium adsorption (P (L)A degrees-based) and absorption (K (OA)-based) models, as well as a steady-state absorption model including an equilibrium and a non-equilibrium term, both being functions of log K (OA), were used to predict the fraction I broken vertical bar of PBDEs associated with the particle phase. The steady-state model proved to be superior to predict G/P partitioning of BDE-209. The distribution of particle-bound PBDEs across size fractions < 0.95, 0.95-1.5, 1.5-3.0, 3.0-7.2, and > 7.2 mu m indicated a positive correlation between the mass median aerodynamic diameter and log P (L)A degrees for the less brominated congeners, whereas a negative correlation was observed for the high brominated congeners. The potential source regions of PBDEs were acknowledged as a combination of long-range transport with short-distance sources.

Návaznosti

GAP503/11/1230, projekt VaV

Název: Perzistentní organické polutanty v atmosférických aerosolech: Procesy, které ovlivňují dálkový transport v Evropě.

Investor: Grantová agentura ČR, Perzistentní organické polutanty v atmosférických aerosolech: procesy, které ovlivňují dálkový transport v Evropě

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

BESIS, Athanasios, Gerhard LAMMEL, Petr KUKUČKA, Constantini SAMARA, Aysun SOFUOGLU, Yetkin DUMANOGLU, Kostas ELEFTHERIADIS, Giorgos KOUVARAKIS, Sait C. SOFUOGLU, Vassiliki VASSILATOU a Dimitra VOUTSA. Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution. Environmental Science and Pollution Research. HEIDELBERG: SPRINGER HEIDELBERG, 2017, roč. 24, č. 36, s. 28102-28120. ISSN 0944-1344. Dostupné z: https://dx.doi.org/10.1007/s11356-017-0285-7.

@article{1409135,
   author = {Besis, Athanasios and Lammel, Gerhard and Kukučka, Petr and Samara, Constantini and Sofuoglu, Aysun and Dumanoglu, Yetkin and Eleftheriadis, Kostas and Kouvarakis, Giorgos and Sofuoglu, Sait C. and Vassilatou, Vassiliki and Voutsa, Dimitra},
   article_location = {HEIDELBERG},
   article_number = {36},
   doi = {http://dx.doi.org/10.1007/s11356-017-0285-7},
   keywords = {Absorption/adsorption models; Gas/particle partitioning; Long-range transport; Aerosol mass size distribution},
   language = {eng},
   issn = {0944-1344},
   journal = {Environmental Science and Pollution Research},
   title = {Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution},
   url = {https://link.springer.com/article/10.1007%2Fs11356-017-0285-7},
   volume = {24},
   year = {2017}
}

TY  - JOUR
ID  - 1409135
AU  - Besis, Athanasios - Lammel, Gerhard - Kukučka, Petr - Samara, Constantini - Sofuoglu, Aysun - Dumanoglu, Yetkin - Eleftheriadis, Kostas - Kouvarakis, Giorgos - Sofuoglu, Sait C. - Vassilatou, Vassiliki - Voutsa, Dimitra
PY  - 2017
TI  - Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution
JF  - Environmental Science and Pollution Research
VL  - 24
IS  - 36
SP  - 28102-28120
EP  - 28102-28120
PB  - SPRINGER HEIDELBERG
SN  - 09441344
KW  - Absorption/adsorption models
KW  - Gas/particle partitioning
KW  - Long-range transport
KW  - Aerosol mass size distribution
UR  - https://link.springer.com/article/10.1007%2Fs11356-017-0285-7
L2  - https://link.springer.com/article/10.1007%2Fs11356-017-0285-7
N2  - The occurrence and atmospheric behavior of tri- to deca-polybrominated diphenyl ethers (PBDEs) were investigated during a 2-week campaign concurrently conducted in July 2012 at four background sites around the Aegean Sea. The study focused on the gas/particle (G/P) partitioning at three sites (Ag. Paraskevi/central Greece/suburban, Finokalia/southern Greece/remote coastal, and Urla/Turkey/rural coastal) and on the size distribution at two sites (Neochorouda/northern Greece/rural inland and Finokalia/southern Greece/remote coastal). The lowest mean total (G + P) concentrations of a(7)PBDE (BDE-28, BDE-47, BDE-66, BDE-99, BDE-100, BDE-153, BDE-154) and BDE-209 (0.81 and 0.95 pg m(-3), respectively) were found at the remote site Finokalia. Partitioning coefficients, K (P), were calculated, and their linear relationships with ambient temperature and the physicochemical properties of the analyzed PBDE congeners, i.e., the subcooled liquid pressure (P (L)A degrees) and the octanol-air partition coefficient (K (OA)), were investigated. The equilibrium adsorption (P (L)A degrees-based) and absorption (K (OA)-based) models, as well as a steady-state absorption model including an equilibrium and a non-equilibrium term, both being functions of log K (OA), were used to predict the fraction I broken vertical bar of PBDEs associated with the particle phase. The steady-state model proved to be superior to predict G/P partitioning of BDE-209. The distribution of particle-bound PBDEs across size fractions < 0.95, 0.95-1.5, 1.5-3.0, 3.0-7.2, and > 7.2 mu m indicated a positive correlation between the mass median aerodynamic diameter and log P (L)A degrees for the less brominated congeners, whereas a negative correlation was observed for the high brominated congeners. The potential source regions of PBDEs were acknowledged as a combination of long-range transport with short-distance sources.
ER  -

BESIS, Athanasios, Gerhard LAMMEL, Petr KUKUČKA, Constantini SAMARA, Aysun SOFUOGLU, Yetkin DUMANOGLU, Kostas ELEFTHERIADIS, Giorgos KOUVARAKIS, Sait C. SOFUOGLU, Vassiliki VASSILATOU a Dimitra VOUTSA. Polybrominated diphenyl ethers (PBDEs) in background air around the Aegean: implications for phase partitioning and size distribution. \textit{Environmental Science and Pollution Research}. HEIDELBERG: SPRINGER HEIDELBERG, 2017, roč.~24, č.~36, s.~28102-28120. ISSN~0944-1344. Dostupné z: https://dx.doi.org/10.1007/s11356-017-0285-7.

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