Currently and recently used pesticides in Central European
arable soils

J 2018

Currently and recently used pesticides in Central European arable soils

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK et. al.

Základní údaje

Originální název

Currently and recently used pesticides in Central European arable soils

Autoři

HVĚZDOVÁ, Martina (203 Česká republika, domácí), Petra KOSUBOVÁ (203 Česká republika), Monika KOSIKOVA (203 Česká republika), Kerstin BRANDSTÄTTER-SCHERR (40 Rakousko), Zdeněk ŠIMEK (203 Česká republika, domácí), Lukas BRODSKY (203 Česká republika), Marek ŠUDOMA (203 Česká republika, domácí), Lucia ŠKULCOVÁ (703 Slovensko, domácí), Milan SÁŇKA (203 Česká republika, domácí), Markéta SVOBODOVÁ (203 Česká republika, domácí), Lucia KRKOŠKOVÁ (203 Česká republika, domácí), Jana VAŠÍČKOVÁ (203 Česká republika, domácí), Natália NEUWIRTHOVÁ (703 Slovensko, domácí), Lucie BIELSKÁ (203 Česká republika, domácí) a Jakub HOFMAN (203 Česká republika, garant, domácí)

Vydání

Science of the Total Environment, AMSTERDAM, Elsevier, 2018, 0048-9697

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.589

Kód RIV

RIV/00216224:14310/18:00100965

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.scitotenv.2017.09.049

UT WoS

000414160500038

Klíčová slova anglicky

Arable soil monitoring; Multi-residue pesticide analysis; Currently used pesticides; Pesticide transformation products; Triazine herbicides; Conazole fungicides

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 30. 5. 2018 11:24, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Although large amounts of pesticides are used annually and amajority enters the soil to formshort-or long-term residues, extensive soil surveys for currently used pesticides (CUPs) are scarce. To determine the status of CUPs' occurrence in arable land in Central Europe, 51 CUPs and 9 transformation products (TPs) were analysed in 75 arable soils in the Czech Republic (CR) several months after the last pesticide application. Moreover, two banned triazines (simazine and atrazine) and their TPs were analysed because of their frequent detection in CR waters. Multi-residue pesticide analysis on LC-MS/MS after soil QuEChERS extraction was used. The soils contained multiple pesticide residues frequently (e.g. 51% soils with >= 5 pesticides). The levels were also noticeable (e.g. 36% soils with >= 3 pesticides exceeding the threshold of 0.01 mg/kg). After triazine herbicides (89% soils), conazole fungicides showed the second most frequent occurrence (73% soils) and also high levels (53% soils with total conazoles above 0.01 mg/kg). Frequent occurrence was found also for chloroacetanilide TPs (25% of soils), fenpropidin (20%) and diflufenican (17%). With the exception of triazines' negative correlation to soil pH, no clear relationships were found between pesticide occurrence and soil properties. Association of simazine TPs with terbuthylazine and its target crops proved the frequent residues of this banned compound originate from terbuthylazine impurities. In contrast, frequent atrazine-2-hydroxy residue is probably a legacy of high atrazine usage in the past. The occurrence and levels of compounds were closely associated with their solubility, hydrophobicity and half-life. The results showed links to CR water-monitoring findings. This study represents the first extensive survey of multiple pesticide residues in Central European arable soils, including an insight into their relationships to site and pesticide properties.

Návaznosti

GA15-20065S, projekt VaV

Název: Osud a biodostupnost v současnosti používaných a nových pesticidů v zemědělsky využívaných fluvizemích - vliv vlastností půd a pesticidů

Investor: Grantová agentura ČR, Osud a biodostupnost v současnosti používaných a nových pesticidů v zemědělsky využívaných fluvizemích - vliv vlastností půd a pesticidů

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK, Lukas BRODSKY, Marek ŠUDOMA, Lucia ŠKULCOVÁ, Milan SÁŇKA, Markéta SVOBODOVÁ, Lucia KRKOŠKOVÁ, Jana VAŠÍČKOVÁ, Natália NEUWIRTHOVÁ, Lucie BIELSKÁ a Jakub HOFMAN. Currently and recently used pesticides in Central European arable soils. Science of the Total Environment. AMSTERDAM: Elsevier, 2018, roč. 613, February, s. 361-370. ISSN 0048-9697. Dostupné z: https://dx.doi.org/10.1016/j.scitotenv.2017.09.049.

@article{1419092,
   author = {Hvězdová, Martina and Kosubová, Petra and Kosikova, Monika and BrandstätterandScherr, Kerstin and Šimek, Zdeněk and Brodsky, Lukas and Šudoma, Marek and Škulcová, Lucia and Sáňka, Milan and Svobodová, Markéta and Krkošková, Lucia and Vašíčková, Jana and Neuwirthová, Natália and Bielská, Lucie and Hofman, Jakub},
   article_location = {AMSTERDAM},
   article_number = {February},
   doi = {http://dx.doi.org/10.1016/j.scitotenv.2017.09.049},
   keywords = {Arable soil monitoring; Multi-residue pesticide analysis; Currently used pesticides; Pesticide transformation products; Triazine herbicides; Conazole fungicides},
   language = {eng},
   issn = {0048-9697},
   journal = {Science of the Total Environment},
   title = {Currently and recently used pesticides in Central European arable soils},
   url = {https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub},
   volume = {613},
   year = {2018}
}

TY  - JOUR
ID  - 1419092
AU  - Hvězdová, Martina - Kosubová, Petra - Kosikova, Monika - Brandstätter-Scherr, Kerstin - Šimek, Zdeněk - Brodsky, Lukas - Šudoma, Marek - Škulcová, Lucia - Sáňka, Milan - Svobodová, Markéta - Krkošková, Lucia - Vašíčková, Jana - Neuwirthová, Natália - Bielská, Lucie - Hofman, Jakub
PY  - 2018
TI  - Currently and recently used pesticides in Central European arable soils
JF  - Science of the Total Environment
VL  - 613
IS  - February
SP  - 361-370
EP  - 361-370
PB  - Elsevier
SN  - 00489697
KW  - Arable soil monitoring
KW  - Multi-residue pesticide analysis
KW  - Currently used pesticides
KW  - Pesticide transformation products
KW  - Triazine herbicides
KW  - Conazole fungicides
UR  - https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub
L2  - https://www.sciencedirect.com/science/article/pii/S0048969717323926?via%3Dihub
N2  - Although large amounts of pesticides are used annually and amajority enters the soil to formshort-or long-term residues, extensive soil surveys for currently used pesticides (CUPs) are scarce. To determine the status of CUPs' occurrence in arable land in Central Europe, 51 CUPs and 9 transformation products (TPs) were analysed in 75 arable soils in the Czech Republic (CR) several months after the last pesticide application. Moreover, two banned triazines (simazine and atrazine) and their TPs were analysed because of their frequent detection in CR waters. Multi-residue pesticide analysis on LC-MS/MS after soil QuEChERS extraction was used. The soils contained multiple pesticide residues frequently (e.g. 51% soils with >= 5 pesticides). The levels were also noticeable (e.g. 36% soils with >= 3 pesticides exceeding the threshold of 0.01 mg/kg). After triazine herbicides (89% soils), conazole fungicides showed the second most frequent occurrence (73% soils) and also high levels (53% soils with total conazoles above 0.01 mg/kg). Frequent occurrence was found also for chloroacetanilide TPs (25% of soils), fenpropidin (20%) and diflufenican (17%). With the exception of triazines' negative correlation to soil pH, no clear relationships were found between pesticide occurrence and soil properties. Association of simazine TPs with terbuthylazine and its target crops proved the frequent residues of this banned compound originate from terbuthylazine impurities. In contrast, frequent atrazine-2-hydroxy residue is probably a legacy of high atrazine usage in the past. The occurrence and levels of compounds were closely associated with their solubility, hydrophobicity and half-life. The results showed links to CR water-monitoring findings. This study represents the first extensive survey of multiple pesticide residues in Central European arable soils, including an insight into their relationships to site and pesticide properties.
ER  -

HVĚZDOVÁ, Martina, Petra KOSUBOVÁ, Monika KOSIKOVA, Kerstin BRANDSTÄTTER-SCHERR, Zdeněk ŠIMEK, Lukas BRODSKY, Marek ŠUDOMA, Lucia ŠKULCOVÁ, Milan SÁŇKA, Markéta SVOBODOVÁ, Lucia KRKOŠKOVÁ, Jana VAŠÍČKOVÁ, Natália NEUWIRTHOVÁ, Lucie BIELSKÁ a Jakub HOFMAN. Currently and recently used pesticides in Central European arable soils. \textit{Science of the Total Environment}. AMSTERDAM: Elsevier, 2018, roč.~613, February, s.~361-370. ISSN~0048-9697. Dostupné z: https://dx.doi.org/10.1016/j.scitotenv.2017.09.049.

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