Retention performance of three widely used SPE sorbents for the
extraction of perfluoroalkyl substances from seawater

J 2018

Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater

BRUMOVSKÝ, Miroslav, Jitka BEČANOVÁ, Pavlína KARÁSKOVÁ a Luca NIZZETTO

Základní údaje

Originální název

Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater

Autoři

BRUMOVSKÝ, Miroslav (203 Česká republika, garant, domácí), Jitka BEČANOVÁ (203 Česká republika, domácí), Pavlína KARÁSKOVÁ (203 Česká republika, domácí) a Luca NIZZETTO (380 Itálie, domácí)

Vydání

Chemosphere, OXFORD, Elsevier Science, 2018, 0045-6535

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10511 Environmental sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.108

Kód RIV

RIV/00216224:14310/18:00102890

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.chemosphere.2017.10.174

UT WoS

000423890500031

Klíčová slova anglicky

Per- and polyfluoroalkyl substances; Oasis (R) HLB; Oasis (R) WAX; Strata (TM)-X; Recovery; Seawater

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 1. 6. 2018 19:59, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Some per- and polyfluoroalkyl substances (PFASs) have been detected ubiquitously in the environment. Owing to the polar character conferred by the presence of the carboxylic or sulfonic acid groups and their resistance to degradation, aquatic environments became their major reservoirs, including marine waters. The procedure of PFAS analysis in aqueous matrices consists usually of solid-phase extraction (SPE) followed by high-performance liquid chromatography coupled to tandem mass spectrometry. Moreover, passive sampling approach using various SPE sorbents may be applied. This study deals with the assessment of retention characteristics of a selected group of PFASs in marine water on three sorbent media widely used in SPE or passive sampling techniques. The influence of type of sorbent, matrix pH, salinity and eluent on the PFAS recovery from aquatic samples was investigated. The best overall extraction conditions were found to be at pH 8 and 50%/100% matrix seawater content using Oasis HLB/ Stratarm-X as SPE sorbents and methanol as eluent. The matrix properties found to be the most appropriate for extraction of investigated PFASs from aqueous samples (i.e., pH and salinity levels) match well the natural properties of marine and brackish waters. Acid-base behavior was found to be the main driver influencing the recovery of PFASs. These research findings can be used to optimize PFAS extraction conditions from aquatic samples and also to develop efficient extraction procedures for multiresidual analyses.

Návaznosti

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

BRUMOVSKÝ, Miroslav, Jitka BEČANOVÁ, Pavlína KARÁSKOVÁ a Luca NIZZETTO. Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater. Chemosphere. OXFORD: Elsevier Science, 2018, roč. 193, February, s. 259-269. ISSN 0045-6535. Dostupné z: https://dx.doi.org/10.1016/j.chemosphere.2017.10.174.

@article{1419343,
   author = {Brumovský, Miroslav and Bečanová, Jitka and Karásková, Pavlína and Nizzetto, Luca},
   article_location = {OXFORD},
   article_number = {February},
   doi = {http://dx.doi.org/10.1016/j.chemosphere.2017.10.174},
   keywords = {Per- and polyfluoroalkyl substances; Oasis (R) HLB; Oasis (R) WAX; Strata (TM)-X; Recovery; Seawater},
   language = {eng},
   issn = {0045-6535},
   journal = {Chemosphere},
   title = {Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater},
   url = {https://www.sciencedirect.com/science/article/pii/S0045653517317514?via%3Dihub},
   volume = {193},
   year = {2018}
}

TY  - JOUR
ID  - 1419343
AU  - Brumovský, Miroslav - Bečanová, Jitka - Karásková, Pavlína - Nizzetto, Luca
PY  - 2018
TI  - Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater
JF  - Chemosphere
VL  - 193
IS  - February
SP  - 259-269
EP  - 259-269
PB  - Elsevier Science
SN  - 00456535
KW  - Per- and polyfluoroalkyl substances
KW  - Oasis (R) HLB
KW  - Oasis (R) WAX
KW  - Strata (TM)-X
KW  - Recovery
KW  - Seawater
UR  - https://www.sciencedirect.com/science/article/pii/S0045653517317514?via%3Dihub
L2  - https://www.sciencedirect.com/science/article/pii/S0045653517317514?via%3Dihub
N2  - Some per- and polyfluoroalkyl substances (PFASs) have been detected ubiquitously in the environment. Owing to the polar character conferred by the presence of the carboxylic or sulfonic acid groups and their resistance to degradation, aquatic environments became their major reservoirs, including marine waters. The procedure of PFAS analysis in aqueous matrices consists usually of solid-phase extraction (SPE) followed by high-performance liquid chromatography coupled to tandem mass spectrometry. Moreover, passive sampling approach using various SPE sorbents may be applied. This study deals with the assessment of retention characteristics of a selected group of PFASs in marine water on three sorbent media widely used in SPE or passive sampling techniques. The influence of type of sorbent, matrix pH, salinity and eluent on the PFAS recovery from aquatic samples was investigated. The best overall extraction conditions were found to be at pH 8 and 50%/100% matrix seawater content using Oasis HLB/ Stratarm-X as SPE sorbents and methanol as eluent. The matrix properties found to be the most appropriate for extraction of investigated PFASs from aqueous samples (i.e., pH and salinity levels) match well the natural properties of marine and brackish waters. Acid-base behavior was found to be the main driver influencing the recovery of PFASs. These research findings can be used to optimize PFAS extraction conditions from aquatic samples and also to develop efficient extraction procedures for multiresidual analyses.
ER  -

BRUMOVSKÝ, Miroslav, Jitka BEČANOVÁ, Pavlína KARÁSKOVÁ a Luca NIZZETTO. Retention performance of three widely used SPE sorbents for the extraction of perfluoroalkyl substances from seawater. \textit{Chemosphere}. OXFORD: Elsevier Science, 2018, roč.~193, February, s.~259-269. ISSN~0045-6535. Dostupné z: https://dx.doi.org/10.1016/j.chemosphere.2017.10.174.

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