Bambusuril Macrocycles Bind Sulfide and Hydrosulfide Anions in Water

VAZQUEZ GONZALVEZ, Julian a Vladimír ŠINDELÁŘ. Bambusuril Macrocycles Bind Sulfide and Hydrosulfide Anions in Water. In 9th Barrande-Vltava French-Czech Chemistry meeting, August 27-28, 2018, Strasbourg, France, 2018. 2018.

Základní údaje

Originální název

Bambusuril Macrocycles Bind Sulfide and Hydrosulfide Anions in Water

Autoři

VAZQUEZ GONZALVEZ, Julian a Vladimír ŠINDELÁŘ

Vydání

9th Barrande-Vltava French-Czech Chemistry meeting, August 27-28, 2018, Strasbourg, France, 2018. 2018

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Další údaje

Typ výsledku

Prezentace na konferencích

Obor

10401 Organic chemistry

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Organizační jednotka

Přírodovědecká fakulta

Příznaky

Mezinárodní význam

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Anotace

V originále

Hydrogen sulfide (H2S) has become an important target for research due to its physiological properties and potential applications in medicine. Many synthetic molecules have been reported as exogenous H2S sources, which rely on chemical reactions for the delivery of the H2S. Bambusurils (BU) are a family of host macrocycles that bind inorganic and organic anions with high affinity and selectivity in both organic and aqueous media. In this work, supramolecular binding of sulfide (S2-) and hydrosulfide (HS-) anions by a synthetic receptor in water have been studied for the first time. Bambusuril macrocycles (BU) were used to stabilize these anions in its cavity following by their release into water.