Controlled photorelease of alkynoic acids and their
decarboxylative deprotection for copper-catalyzed azide/alkyne
cycloaddition

J 2018

Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition

VOHRADSKÁ, Nikoleta, Esther Maria MARQUEZ SANCHEZ - CARNERERO, Tomáš PASTIERIK, Ctibor MAZAL, Petr KLÁN et. al.

Základní údaje

Originální název

Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition

Autoři

VOHRADSKÁ, Nikoleta (703 Slovensko, domácí), Esther Maria MARQUEZ SANCHEZ - CARNERERO (724 Španělsko, domácí), Tomáš PASTIERIK (703 Slovensko, domácí), Ctibor MAZAL (203 Česká republika, domácí) a Petr KLÁN (203 Česká republika, garant, domácí)

Vydání

Chemical communications, Cambridge, Royal Society of Chemistry, 2018, 1359-7345

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 6.164

Kód RIV

RIV/00216224:14310/18:00101606

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1039/c8cc03341b

UT WoS

000433510000012

Klíčová slova anglicky

PHOTOREMOVABLE PROTECTING GROUPS; ONE-POT SYNTHESIS; COUPLING REACTIONS; BORON DIPYRROMETHENE; CARBOXYLIC-ACIDS; CLICK CHEMISTRY; PROPIOLIC ACID; ARYL IODIDES; GREEN LIGHT

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 18. 1. 2019 16:02, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

A controlled photorelease of alkynoic acids from the meso-methyl BODIPY photoremovable protecting group facilitates their subsequent efficient decarboxylation to give terminal alkynes for a Cu-I-catalyzed azide/ alkyne cycloaddition. The quantum efficiencies of the photochemical step and the kinetics of the click reaction step are reported.

Návaznosti

GA13-25775S, projekt VaV

Název: Vývoj viditelným světlem aktivovatelných skupin a fluorescenčních značek pro chemii a biologii

Investor: Grantová agentura ČR, Vývoj viditelným světlem aktivovatelných skupin a fluorescenčních značek pro chemii a biologii

Citovat

VOHRADSKÁ, Nikoleta, Esther Maria MARQUEZ SANCHEZ - CARNERERO, Tomáš PASTIERIK, Ctibor MAZAL a Petr KLÁN. Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition. Chemical communications. Cambridge: Royal Society of Chemistry, 2018, roč. 54, č. 44, s. 5558-5561. ISSN 1359-7345. Dostupné z: https://dx.doi.org/10.1039/c8cc03341b.

@article{1488114,
   author = {Vohradská, Nikoleta and Marquez Sanchez and Carnerero, Esther Maria and Pastierik, Tomáš and Mazal, Ctibor and Klán, Petr},
   article_location = {Cambridge},
   article_number = {44},
   doi = {http://dx.doi.org/10.1039/c8cc03341b},
   keywords = {PHOTOREMOVABLE PROTECTING GROUPS; ONE-POT SYNTHESIS; COUPLING REACTIONS; BORON DIPYRROMETHENE; CARBOXYLIC-ACIDS; CLICK CHEMISTRY; PROPIOLIC ACID; ARYL IODIDES; GREEN LIGHT},
   language = {eng},
   issn = {1359-7345},
   journal = {Chemical communications},
   title = {Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition},
   url = {https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract},
   volume = {54},
   year = {2018}
}

TY  - JOUR
ID  - 1488114
AU  - Vohradská, Nikoleta - Marquez Sanchez - Carnerero, Esther Maria - Pastierik, Tomáš - Mazal, Ctibor - Klán, Petr
PY  - 2018
TI  - Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition
JF  - Chemical communications
VL  - 54
IS  - 44
SP  - 5558-5561
EP  - 5558-5561
PB  - Royal Society of Chemistry
SN  - 13597345
KW  - PHOTOREMOVABLE PROTECTING GROUPS
KW  - ONE-POT SYNTHESIS
KW  - COUPLING REACTIONS
KW  - BORON DIPYRROMETHENE
KW  - CARBOXYLIC-ACIDS
KW  - CLICK CHEMISTRY
KW  - PROPIOLIC ACID
KW  - ARYL IODIDES
KW  - GREEN LIGHT
UR  - https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract
L2  - https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC03341B#!divAbstract
N2  - A controlled photorelease of alkynoic acids from the meso-methyl BODIPY photoremovable protecting group facilitates their subsequent efficient decarboxylation to give terminal alkynes for a Cu-I-catalyzed azide/ alkyne cycloaddition. The quantum efficiencies of the photochemical step and the kinetics of the click reaction step are reported.
ER  -

VOHRADSKÁ, Nikoleta, Esther Maria MARQUEZ SANCHEZ - CARNERERO, Tomáš PASTIERIK, Ctibor MAZAL a Petr KLÁN. Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition. \textit{Chemical communications}. Cambridge: Royal Society of Chemistry, 2018, roč.~54, č.~44, s.~5558-5561. ISSN~1359-7345. Dostupné z: https://dx.doi.org/10.1039/c8cc03341b.

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