Corrosion of nickel-based structural materials for nuclear
reactors by molten fluoride salt: From bulk content of
corrosion products to elemental imaging of corrosion changes

J 2018

Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes

WARCHILOVÁ, Tereza, Veronika DILLINGEROVÁ, Radek ŠKODA, T. SIMO, O. MATAL et. al.

Základní údaje

Originální název

Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes

Autoři

WARCHILOVÁ, Tereza (203 Česká republika, domácí), Veronika DILLINGEROVÁ (703 Slovensko, domácí), Radek ŠKODA (203 Česká republika, domácí), T. SIMO (203 Česká republika), O. MATAL (203 Česká republika), Tomáš VACULOVIČ (203 Česká republika, garant, domácí) a Viktor KANICKÝ (203 Česká republika, domácí)

Vydání

Spectrochimica Acta, Part B: Atomic Spectroscopy, Oxford, Elsevier, 2018, 0584-8547

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.101

Kód RIV

RIV/00216224:14310/18:00106464

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.sab.2018.06.010

UT WoS

000445311800014

Klíčová slova anglicky

Molten fluoride salt; LA-ICP-MS; EPMA; Corrosion; Elemental imaging; Ni-based structural material

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 4. 2024 14:17, Mgr. Michal Petr

Anotace

V originále

This work is focused on the study of corrosion treatment of molten fluoride salt (MFS) on three candidate structural materials (Ni, ferritic steel with protective Ni coating, and Ni-based alloy). The samples were exposed to an MFS mixture (60 mol% LiF + 40 mol% NaF) at a temperature of 680 degrees C for 112, 350 and 1000 h. Their corrosion resistance was tested by the determination of the content of corrosion products in MFS by ICP-OES (Inductively Coupled Plasma with Optical Emission Spectrometry) analysis and comparison of elemental ratios. Distinctive differences in the ratios were found for ferritic steel with protective Ni coating. Morphological changes induced by MFS treatment were revealed and studied by EPMA (Electron Probe Micro Analysis) and LA-ICP-MS (Laser Ablation Inductively Coupled Plasma of Mass Spectrometry). Elemental maps of the corroded area were acquired by both methods. The analyses of corrosion products show that the best candidate material is nickel.

Návaznosti

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

WARCHILOVÁ, Tereza, Veronika DILLINGEROVÁ, Radek ŠKODA, T. SIMO, O. MATAL, Tomáš VACULOVIČ a Viktor KANICKÝ. Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes. Spectrochimica Acta, Part B: Atomic Spectroscopy. Oxford: Elsevier, 2018, roč. 148, OCT, s. 113-117. ISSN 0584-8547. Dostupné z: https://dx.doi.org/10.1016/j.sab.2018.06.010.

@article{1503162,
   author = {Warchilová, Tereza and Dillingerová, Veronika and Škoda, Radek and Simo, T. and Matal, O. and Vaculovič, Tomáš and Kanický, Viktor},
   article_location = {Oxford},
   article_number = {OCT},
   doi = {http://dx.doi.org/10.1016/j.sab.2018.06.010},
   keywords = {Molten fluoride salt; LA-ICP-MS; EPMA; Corrosion; Elemental imaging; Ni-based structural material},
   language = {eng},
   issn = {0584-8547},
   journal = {Spectrochimica Acta, Part B: Atomic Spectroscopy},
   title = {Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes},
   url = {http://dx.doi.org/10.1016/j.sab.2018.06.010},
   volume = {148},
   year = {2018}
}

TY  - JOUR
ID  - 1503162
AU  - Warchilová, Tereza - Dillingerová, Veronika - Škoda, Radek - Simo, T. - Matal, O. - Vaculovič, Tomáš - Kanický, Viktor
PY  - 2018
TI  - Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes
JF  - Spectrochimica Acta, Part B: Atomic Spectroscopy
VL  - 148
IS  - OCT
SP  - 113-117
EP  - 113-117
PB  - Elsevier
SN  - 05848547
KW  - Molten fluoride salt
KW  - LA-ICP-MS
KW  - EPMA
KW  - Corrosion
KW  - Elemental imaging
KW  - Ni-based structural material
UR  - http://dx.doi.org/10.1016/j.sab.2018.06.010
N2  - This work is focused on the study of corrosion treatment of molten fluoride salt (MFS) on three candidate structural materials (Ni, ferritic steel with protective Ni coating, and Ni-based alloy). The samples were exposed to an MFS mixture (60 mol% LiF + 40 mol% NaF) at a temperature of 680 degrees C for 112, 350 and 1000 h. Their corrosion resistance was tested by the determination of the content of corrosion products in MFS by ICP-OES (Inductively Coupled Plasma with Optical Emission Spectrometry) analysis and comparison of elemental ratios. Distinctive differences in the ratios were found for ferritic steel with protective Ni coating. Morphological changes induced by MFS treatment were revealed and studied by EPMA (Electron Probe Micro Analysis) and LA-ICP-MS (Laser Ablation Inductively Coupled Plasma of Mass Spectrometry). Elemental maps of the corroded area were acquired by both methods. The analyses of corrosion products show that the best candidate material is nickel.
ER  -

WARCHILOVÁ, Tereza, Veronika DILLINGEROVÁ, Radek ŠKODA, T. SIMO, O. MATAL, Tomáš VACULOVIČ a Viktor KANICKÝ. Corrosion of nickel-based structural materials for nuclear reactors by molten fluoride salt: From bulk content of corrosion products to elemental imaging of corrosion changes. \textit{Spectrochimica Acta, Part B: Atomic Spectroscopy}. Oxford: Elsevier, 2018, roč.~148, OCT, s.~113-117. ISSN~0584-8547. Dostupné z: https://dx.doi.org/10.1016/j.sab.2018.06.010.

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