Alumazene Reactivity with Quinolinols - Addition and
Substitution Reactions on the Al3N3 Ring

J 2018

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA et. al.

Základní údaje

Originální název

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

Autoři

KOLLHAMMEROVÁ, Iva (203 Česká republika, domácí), Michal BABIAK (703 Slovensko, domácí), Marek NEČAS (203 Česká republika, domácí), Petr TÁBORSKÝ (203 Česká republika, domácí), Josef KUČERA (203 Česká republika, domácí) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

Acta Chimica Slovenica, LJUBLJANA, SLOVENSKO KEMIJSKO DRUSTVO, 2018, 1318-0207

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Slovinsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.076

Kód RIV

RIV/00216224:14310/18:00106568

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.17344/acsi.2018.4624

UT WoS

000453240200020

Klíčová slova anglicky

Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence

Štítky

CF SAXS, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 4. 2024 14:28, Mgr. Michal Petr

Anotace

V originále

Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.

Návaznosti

LM2015043, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA a Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. Acta Chimica Slovenica. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, roč. 65, č. 4, s. 955-963. ISSN 1318-0207. Dostupné z: https://dx.doi.org/10.17344/acsi.2018.4624.

@article{1504916,
   author = {Kollhammerová, Iva and Babiak, Michal and Nečas, Marek and Táborský, Petr and Kučera, Josef and Pinkas, Jiří},
   article_location = {LJUBLJANA},
   article_number = {4},
   doi = {http://dx.doi.org/10.17344/acsi.2018.4624},
   keywords = {Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence},
   language = {eng},
   issn = {1318-0207},
   journal = {Acta Chimica Slovenica},
   title = {Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring},
   url = {http://dx.doi.org/10.17344/acsi.2018.4624},
   volume = {65},
   year = {2018}
}

TY  - JOUR
ID  - 1504916
AU  - Kollhammerová, Iva - Babiak, Michal - Nečas, Marek - Táborský, Petr - Kučera, Josef - Pinkas, Jiří
PY  - 2018
TI  - Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring
JF  - Acta Chimica Slovenica
VL  - 65
IS  - 4
SP  - 955-963
EP  - 955-963
PB  - SLOVENSKO KEMIJSKO DRUSTVO
SN  - 13180207
KW  - Alumazene
KW  - crystal structure
KW  - quinolin-8-ol
KW  - 2-methylquinolin-8-ol
KW  - luminescence
UR  - http://dx.doi.org/10.17344/acsi.2018.4624
N2  - Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.
ER  -

KOLLHAMMEROVÁ, Iva, Michal BABIAK, Marek NEČAS, Petr TÁBORSKÝ, Josef KUČERA a Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. \textit{Acta Chimica Slovenica}. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, roč.~65, č.~4, s.~955-963. ISSN~1318-0207. Dostupné z: https://dx.doi.org/10.17344/acsi.2018.4624.

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