| KONHEFR, Martin, Adam C. SEDGWICK, Tony D. JAMES, Karel LACINA, Petr SKLÁDAL, Budi Riza PUTRA, Christian HARITO, Dmitry V. BAVYKIN, Frank C. WALSH, Paul R. RAITHBY, Gabriele KOCIOK-KÖHN a Frank MARKEN. Voltammetric characterisation of diferrocenylborinic acid in organic solution and in aqueous media when immobilised into a titanate nanosheet film. Dalton Transactions. Royal Society of Chemistry, 2019, roč. 48, č. 30, s. 11200-11207. ISSN 1477-9226. Dostupné z: https://dx.doi.org/10.1039/c9dt00881k. |
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@article{1535559,
author = {Konhefr, Martin and Sedgwick, Adam C. and James, Tony D. and Lacina, Karel and Skládal, Petr and Putra, Budi Riza and Harito, Christian and Bavykin, Dmitry V. and Walsh, Frank C. and Raithby, Paul R. and KociokandKöhn, Gabriele and Marken, Frank},
article_number = {30},
doi = {http://dx.doi.org/10.1039/c9dt00881k},
keywords = {borinic acid; boronic acid; ferrocene; titanate nanosheets; fluoride; sensing},
language = {eng},
issn = {1477-9226},
journal = {Dalton Transactions},
title = {Voltammetric characterisation of diferrocenylborinic acid in organic solution and in aqueous media when immobilised into a titanate nanosheet film},
url = {https://pubs.rsc.org/en/content/articlepdf/2019/dt/c9dt00881k},
volume = {48},
year = {2019}
}
TY - JOUR
ID - 1535559
AU - Konhefr, Martin - Sedgwick, Adam C. - James, Tony D. - Lacina, Karel - Skládal, Petr - Putra, Budi Riza - Harito, Christian - Bavykin, Dmitry V. - Walsh, Frank C. - Raithby, Paul R. - Kociok-Köhn, Gabriele - Marken, Frank
PY - 2019
TI - Voltammetric characterisation of diferrocenylborinic acid in organic solution and in aqueous media when immobilised into a titanate nanosheet film
JF - Dalton Transactions
VL - 48
IS - 30
SP - 11200-11207
EP - 11200-11207
PB - Royal Society of Chemistry
SN - 14779226
KW - borinic acid
KW - boronic acid
KW - ferrocene
KW - titanate nanosheets
KW - fluoride
KW - sensing
UR - https://pubs.rsc.org/en/content/articlepdf/2019/dt/c9dt00881k
L2 - https://pubs.rsc.org/en/content/articlepdf/2019/dt/c9dt00881k
N2 - Diferrocenylborinic acid (Fc2BOH,1) has been synthesized in good yield via an improved synthetic path. Characterisation by nuclear magnetic resonance (NMR), mass spectrometry (HRMS), infrared spectroscopy (FTIR), X-ray crystallography, and by electrochemical methods reveal two one-electron oxidation processes for the two electronically coupled ferrocenyl moieties. The oxidation of 1 dissolved in organic media is contrasted to the oxidation of 1 in aqueous environments (by incorporation of 1 into a lamellar film of 2D titanate nanosheets on a glassy carbon electrode). Data from cyclic voltammetry and from square wave voltammetry suggest that the bridging boron can bind to nucleophiles (hydroxide, fluoride) upon oxidation of the ferrocenyl groups. A multi-pathway ECE reaction scheme is proposed. Potential applications in sensing are discussed.
ER -
KONHEFR, Martin, Adam C. SEDGWICK, Tony D. JAMES, Karel LACINA, Petr SKLÁDAL, Budi Riza PUTRA, Christian HARITO, Dmitry V. BAVYKIN, Frank C. WALSH, Paul R. RAITHBY, Gabriele KOCIOK-KÖHN a Frank MARKEN. Voltammetric characterisation of diferrocenylborinic acid in organic solution and in aqueous media when immobilised into a titanate nanosheet film. \textit{Dalton Transactions}. Royal Society of Chemistry, 2019, roč.~48, č.~30, s.~11200-11207. ISSN~1477-9226. Dostupné z: https://dx.doi.org/10.1039/c9dt00881k.
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