Morphology Control in AgCu Nanoalloy Synthesis by Molecular
Cu(I) Precursors

J 2019

Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors

VYKOUKAL, Vít, Vitezslav HALASTA, Michal BABIAK, Jiří BURŠÍK, Jiří PINKAS et. al.

Základní údaje

Originální název

Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors

Autoři

VYKOUKAL, Vít (203 Česká republika, domácí), Vitezslav HALASTA (203 Česká republika), Michal BABIAK (703 Slovensko, domácí), Jiří BURŠÍK (203 Česká republika) a Jiří PINKAS (203 Česká republika, garant, domácí)

Vydání

Inorganic Chemistry, Washington, American Chemical Society, 2019, 0020-1669

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.825

Kód RIV

RIV/00216224:14310/19:00108075

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1021/acs.inorgchem.9b02172

UT WoS

000498288300031

Klíčová slova anglicky

AgCu; Nanoalloy; Synthesis; Precursor; Nanoparticles

Štítky

CF CRYO, CF NMR, CF SAXS, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 29. 3. 2020 19:11, Mgr. Marie Šípková, DiS.

Anotace

V originále

As nanoparticle preparation methods employing bottom-up procedures rely on the use of molecular precursors, the chemical composition and bonding of these precursors have a decisive effect on nanoparticle formation and their resulting morphology and properties. We synthesized the Cu(I) complexes [Cu(PPh3)(2) (bea)] (1, bea = benzoate) and [Cu(PPh3)(3) (Hphta)] (2, phta = phthalate) by reducing the corresponding Cu(II) mono- and dicarboxylates with triphenylphosphine. We characterized 1 and 2 by single-crystal X-ray diffraction analysis, elemental analyses, infrared and nuclear magnetic resonance spectroscopy, and mass spectrometry and obtained complete information about their structures in the solid state and in solution. Also, we examined their thermal stability in oleylamine and determined their decomposition temperatures to be used as the minimal reaction temperature in metal nanoparticle synthesis. The complexes 1 and 2 differ in the number of reducing PPh 3 ligands and the strength of carboxylate bonding to the Cu(I) center. Therefore, we employed them in combination with [Ag(NH2C12H25)(2)]NO3 as molecular precursors in the solvothermal hot injection synthesis of AgCu nanoalloys in oleylamine and demonstrated their influence on the elemental distribution, phase composition, particle size distribution, shape, morphology, and optical properties of the resulting nanoparticles. The nanoalloy particles from the benzoate complex 1 were oblate and polydisperse and exhibited two surface plasmons at 393 and 569 nm, which is caused by their Janus-type structure. The nanoparticles prepared from the phthalate complex 2 were round and monodisperse and exhibited one plasmon at 413 nm, as they formed an AgCu solid solution with a random distribution of the elements in a particle.

Návaznosti

GA17-15405S, projekt VaV

Název: Pokročilé experimentální a teoretické přístupy k fázovým diagramům nanoslitin se zahrnutím vlivu velikosti částic

Investor: Grantová agentura ČR, Pokročilé experimentální a teoretické přístupy k fázovým diagramům nanoslitin se zahrnutím vlivu velikosti částic

LM2015041, projekt VaV

Název: CEITEC Nano

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC Nano

LM2015043, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

VYKOUKAL, Vít, Vitezslav HALASTA, Michal BABIAK, Jiří BURŠÍK a Jiří PINKAS. Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors. Inorganic Chemistry. Washington: American Chemical Society, 2019, roč. 58, č. 22, s. 15246-15254. ISSN 0020-1669. Dostupné z: https://dx.doi.org/10.1021/acs.inorgchem.9b02172.

@article{1606437,
   author = {Vykoukal, Vít and Halasta, Vitezslav and Babiak, Michal and Buršík, Jiří and Pinkas, Jiří},
   article_location = {Washington},
   article_number = {22},
   doi = {http://dx.doi.org/10.1021/acs.inorgchem.9b02172},
   keywords = {AgCu; Nanoalloy; Synthesis; Precursor; Nanoparticles},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorganic Chemistry},
   title = {Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors},
   url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02172},
   volume = {58},
   year = {2019}
}

TY  - JOUR
ID  - 1606437
AU  - Vykoukal, Vít - Halasta, Vitezslav - Babiak, Michal - Buršík, Jiří - Pinkas, Jiří
PY  - 2019
TI  - Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors
JF  - Inorganic Chemistry
VL  - 58
IS  - 22
SP  - 15246-15254
EP  - 15246-15254
PB  - American Chemical Society
SN  - 00201669
KW  - AgCu
KW  - Nanoalloy
KW  - Synthesis
KW  - Precursor
KW  - Nanoparticles
UR  - https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02172
L2  - https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b02172
N2  - As nanoparticle preparation methods employing bottom-up procedures rely on the use of molecular precursors, the chemical composition and bonding of these precursors have a decisive effect on nanoparticle formation and their resulting morphology and properties. We synthesized the Cu(I) complexes [Cu(PPh3)(2) (bea)] (1, bea = benzoate) and [Cu(PPh3)(3) (Hphta)] (2, phta = phthalate) by reducing the corresponding Cu(II) mono- and dicarboxylates with triphenylphosphine. We characterized 1 and 2 by single-crystal X-ray diffraction analysis, elemental analyses, infrared and nuclear magnetic resonance spectroscopy, and mass spectrometry and obtained complete information about their structures in the solid state and in solution. Also, we examined their thermal stability in oleylamine and determined their decomposition temperatures to be used as the minimal reaction temperature in metal nanoparticle synthesis. The complexes 1 and 2 differ in the number of reducing PPh 3 ligands and the strength of carboxylate bonding to the Cu(I) center. Therefore, we employed them in combination with [Ag(NH2C12H25)(2)]NO3 as molecular precursors in the solvothermal hot injection synthesis of AgCu nanoalloys in oleylamine and demonstrated their influence on the elemental distribution, phase composition, particle size distribution, shape, morphology, and optical properties of the resulting nanoparticles. The nanoalloy particles from the benzoate complex 1 were oblate and polydisperse and exhibited two surface plasmons at 393 and 569 nm, which is caused by their Janus-type structure. The nanoparticles prepared from the phthalate complex 2 were round and monodisperse and exhibited one plasmon at 413 nm, as they formed an AgCu solid solution with a random distribution of the elements in a particle.
ER  -

VYKOUKAL, Vít, Vitezslav HALASTA, Michal BABIAK, Jiří BURŠÍK a Jiří PINKAS. Morphology Control in AgCu Nanoalloy Synthesis by Molecular Cu(I) Precursors. \textit{Inorganic Chemistry}. Washington: American Chemical Society, 2019, roč.~58, č.~22, s.~15246-15254. ISSN~0020-1669. Dostupné z: https://dx.doi.org/10.1021/acs.inorgchem.9b02172.

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